238244
Iodocyclohexane
98%
Synonym(s):
Cyclohexyl iodide
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About This Item
Empirical Formula (Hill Notation):
C6H11I
CAS Number:
Molecular Weight:
210.06
Beilstein:
1900797
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
98%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.5441 (lit.)
bp
80-81 °C/20 mmHg (lit.)
density
1.624 g/mL at 25 °C (lit.)
functional group
iodo
storage temp.
2-8°C
SMILES string
IC1CCCCC1
InChI
1S/C6H11I/c7-6-4-2-1-3-5-6/h6H,1-5H2
InChI key
FUCOMWZKWIEKRK-UHFFFAOYSA-N
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General description
The photodissociation dynamics of iodocyclohexane has been studied using velocity map imaging. Nickel catalyzed coupling of iodocyclohexane with 1-octyne has been investigated.
Application
Iodocyclohexane has been employed as reagent in demethylation of aryl methyl ethers in DMF under reflux condition.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
158.0 °F - closed cup
Flash Point(C)
70 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Jun Yi et al.
Angewandte Chemie (International ed. in English), 52(47), 12409-12413 (2013-10-12)
A nicked reaction: The title reaction of terminal alkynes with non-activated secondary alkyl iodides and bromides was accomplished for the first time. This reaction provides a new and practical approach for the synthesis of substituted alkynes (see scheme; cod=cyclo-1,5-octadiene).
An efficient method for demethylation of aryl methyl ethers.
Zuo L, et al.
Tetrahedron Letters, 49(25), 4054-4056 (2008)
D K Zaouris et al.
The Journal of chemical physics, 135(9), 094312-094312 (2011-09-15)
The photodissociation dynamics of iodocyclohexane has been studied using velocity map imaging following excitation at many wavelengths within its A-band (230 ≤ λ ≤ 305 nm). This molecule exists in two conformations (axial and equatorial), and one aim of the
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