458139

tert-Butyl hydroperoxide solution

70 wt. % in H₂O

• Synonym(s): TBHP, 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane
• Linear Formula: (CH₃)₃COOH
• CAS Number: 75-91-2
• Molecular Weight: 90.12
• Beilstein: 1098280
• MDL number: MFCD00002130
• UNSPSC Code: 12162002
• PubChem Substance ID: 24869433
• NACRES: NA.23

Properties

• form: liquid
• Quality Level: 200
• reaction suitability: reaction type: C-H Activation; reagent type: catalyst; reagent type: oxidant
• concentration: 12.25-13.31% (active oxygen); 69.0-75.0% (Na₂S₂O₃, titration); 70 wt. % in H₂O
• refractive index: n20/D 1.386
• pH: 4.3
• bp: 96.2 °C
• density: 0.93 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: CC(C)(C)OO
• InChI: 1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
• InChI key: CIHOLLKRGTVIJN-UHFFFAOYSA-N

Description

Application

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts

Versatile reagent for oxidations.

Legal Information

Product of Arkema Inc.

Safety Information

• Pictograms: GHS02,GHS06,GHS08,GHS05,GHS09
• Signal Word: Danger
• Hazard Statements: H226,H242,H302,H311,H314,H317,H330,H335,H341,H411
• Precautionary Statements: P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378
• Hazard Classifications: Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 5.2 - Organic peroxides and self-reacting hazardous materials
• WGK: WGK 3
• Flash Point(F): 107.6 °F - closed cup
• Flash Point(C): 42 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves