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919578

Sigma-Aldrich

PAd2-DalPhos Ni(o-tolyl)Cl

Synonym(s):

(PAd2-Dalphos)Ni()

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About This Item

Empirical Formula (Hill Notation):
C33H43ClNiO6P2
Molecular Weight:
691.78
UNSPSC Code:
12161600
NACRES:
NA.22

form

powder

Quality Level

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

Application

PAd2-DalPhos Ni(o-tolyl)Cl is an air-stable precatalyst developed in the Stradiotto lab for cross coupling of primary heteroarylamines and (hetero)aryl chlorides.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Jillian S K Clark et al.
Angewandte Chemie (International ed. in English), 58(19), 6391-6395 (2019-03-16)
Base-metal catalysts capable of enabling the assembly of heteroatom-dense molecules by cross-coupling of primary heteroarylamines and (hetero)aryl chlorides, while sought-after given the ubiquity of unsymmetrical di(hetero)arylamino fragments in pharmacophores, are unknown. Herein, we disclose the new "double cage" bisphosphine PAd2-DalPhos

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