Skip to Content
MilliporeSigma
All Photos(1)

Key Documents

923443

Sigma-Aldrich

PhMPhos

Synonym(s):

1-Diadamantylphosphino-1′-diphenylphosphinoferrocene

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C42H48FeP2
Molecular Weight:
670.62
UNSPSC Code:
12352200
NACRES:
NA.21

form

powder

Quality Level

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

reagent type: ligand

functional group

phosphine

Application

PhMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing PhMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service