32824
Fluazifop
PESTANAL®, analytical standard
Synonym(s):
2-[4-(5-Trifluoromethyl-2-pyridyloxy)phenoxy]propionic acid
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All Photos(2)
About This Item
Empirical Formula (Hill Notation):
C15H12F3NO4
CAS Number:
Molecular Weight:
327.26
Beilstein:
552236
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24
Recommended Products
grade
analytical standard
Quality Level
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
application(s)
agriculture
environmental
format
neat
SMILES string
CC(Oc1ccc(Oc2ccc(cn2)C(F)(F)F)cc1)C(O)=O
InChI
1S/C15H12F3NO4/c1-9(14(20)21)22-11-3-5-12(6-4-11)23-13-7-2-10(8-19-13)15(16,17)18/h2-9H,1H3,(H,20,21)
InChI key
YUVKUEAFAVKILW-UHFFFAOYSA-N
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General description
Fluazifop is one of the major metabolites of fluazifop-p-butyl, a systemic, post-emergence herbicide used for the control of annual and perennial grass weeds in non-graminaceous crops.
Application
Fluazifop may be used as an analytical reference standard for the determination of the analyte in:
- Rainwater samples by solid-phase extraction (SPE) and liquid chromatography-tandem mass spectrometry (LC-MS/MS).
- Vegetables by acetonitrile-based QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction followed by LC-MS/MS.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Recommended products
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Repr. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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E Bolygo et al.
Fresenius' journal of analytical chemistry, 368(8), 816-819 (2001-03-03)
An LC-MS-MS assay is described for fluazifop residue analysis in crops. The residues are extracted with acidified organic solvent, the esters and conjugates are hydrolysed with 6 M hydrochloric acid, then the extracts are cleaned-up by solid phase extraction using
L Várnagy et al.
Acta veterinaria Hungarica, 47(2), 271-277 (1999-05-27)
Toxicological studies on wild animals play an important role in the ecotoxicological examination of pesticides. The applied model tests enable the assessment of toxicological consequences with particular regard to the life and nutrition of wild animals in the ploughed field
Grazyna Kostka et al.
Toxicology, 178(3), 221-228 (2002-08-09)
The aim of this study was to determine the effect of herbicide fluazifop, on the early occurring changes in rat liver regarded as hepatic markers of peroxisome proliferators (PPs). Fluazifop was administered orally to male Wistar rats at increasing doses
A M Shestopalov et al.
Journal of combinatorial chemistry, 2(1), 24-28 (2000-04-06)
S-Alkylation followed by heterocyclization of trifluoromethyl-3-cyano-2(1H)-pyridinethiones was used for preparation of libraries of S-alkyl trifluoromethylpyridines and thieno[2,3-b]pyridines. The S-alkylation (in water--DMF mixtures) was successful for all 18 alkylating agents employed (yields typically > 50%). S-Alkyl derivatives were further converted to
Persistence studies with the herbicide fluazifop-butyl in Saskatchewan soils under laboratory and field conditions.
A E Smith
Bulletin of environmental contamination and toxicology, 39(1), 150-155 (1987-07-01)
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