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902225

Ir[dFMeppy]2-(4,4′-dCF3bpy)PF6

≥95%

Synonym(s):

Photocatalyst

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About This Item

Empirical Formula (Hill Notation):
C36H22F16IrN4P
Molecular Weight:
1037.75
UNSPSC Code:
41141700
NACRES:
NA.22

Assay

≥95%

form

powder

reaction suitability

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C

Related Categories

Application

Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

A radical approach to the copper oxidative addition problem:Trifluoromethylation of bromoarenes

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747769

[Ir(dtbbpy)(ppy)2]PF6

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(Ir[dF(CF3)ppy]2(dtbpy))PF6

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[Ir{dFCF3ppy}2(bpy)]PF6

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Ir(p-F-ppy)3

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(S)-2-Benzylpiperidine, ≥95%

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Mes-Umemoto reagent, ≥95%

901368

[Ir(dFppy)2(dtbbpy)]PF6

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[Ir(dF(Me)ppy)2(dtbbpy)]PF6

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Ir[dFFppy]2-(4,4′-dCF3bpy)PF6, ≥95%

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904694

Ir(p-CF3-ppy)3, ≥95%

905518

Ir(dFFppy)2(dtbbpy)PF6

905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6, ≥95%

908703

[Ir(p-F(Me)ppy)2-(4,4′-dtbbpy)]PF6, ≥95%

911607

[Ir(dFOMeppy)2-(5,5′-dCF3bpy)]PF6 , ≥95%

912948

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

922897

[Ir(ppy)2(5,5′-Me2bpy)]PF6, ≥95%

925497

[Ir(dFOMeppy)2(dtbbpy)]PF6, ≥95%

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCJ9415

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Chip Le et al.
Science (New York, N.Y.), 360(6392), 1010-1014 (2018-06-02)
Transition metal-catalyzed arene functionalization has been widely used for molecular synthesis over the past century. In this arena, copper catalysis has long been considered a privileged platform due to the propensity of high-valent copper to undergo reductive elimination with a

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