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M0789

Supelco

N-Methyl-bis(trifluoroacetamide)

for GC derivatization, LiChropur™, ≥97.0% (GC)

Synonym(s):

MBTFA (N-methyl-bis(trifluoroacetamide)or BTFA (bis(TFA)), MBTFA

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About This Item

Linear Formula:
CF3CON(CH3)COCF3
CAS Number:
685-27-8
Molecular Weight:
223.07
Beilstein:
1878402
EC Number:
211-680-5
MDL number:
MFCD00000412
UNSPSC Code:
12000000
PubChem Substance ID:
24896572
NACRES:
NA.22

grade

for GC derivatization

Assay

≥97.0% (GC)

form

liquid

quality

LiChropur™

reaction suitability

reagent type: derivatization reagent
reaction type: Acylations

technique(s)

gas chromatography (GC): suitable

refractive index

n20/D 1.346 (lit.)

bp

121-122 °C (lit.)

density

1.547 g/mL at 25 °C

suitability

complies for derivatization

storage temp.

2-8°C

SMILES string

CN(C(=O)C(F)(F)F)C(=O)C(F)(F)F

InChI

1S/C5H3F6NO2/c1-12(2(13)4(6,7)8)3(14)5(9,10)11/h1H3

InChI key

AWGBWLXGUPTXHF-UHFFFAOYSA-N

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Related Categories

Application

Reagent for introducing trifluoroacetyl group.
Suitable for the derivatization of alcohols and carbohydrates(mono-,di-,tri- and tetrasaccharides.

Other Notes

Reagent for trifluoroacetyl.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H226,H314

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

113.0 °F - closed cup

Flash Point(C)

45 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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N Pizarro et al.
Journal of pharmaceutical and biomedical analysis, 21(4), 739-747 (2000-03-04)
We developed a fast and sensitive method for identification and quantification of plasma concentrations of amphetamine using gas chromatography with mass spectrometry detection (GC-MS). Amphetamine-d8 served as internal standard. The method involves a single extraction procedure and an easy treatment
Caroline Raeppel et al.
Journal of chromatography. A, 1218(44), 8123-8129 (2011-10-04)
This work presents a new method to analyse simultaneously by GC-MS 31 pesticides from different chemical classes (2,4 D, 2,4 MCPA, alphacypermethrin, bifenthrin, bromoxynil, buprofezin, carbaryl, carbofuran, clopyralid, cyprodinil, deltamethrin dicamba, dichlobenil, dichlorprop, diflufenican, diuron, fenoxaprop, flazasulfuron, fluroxypyr, ioxynil, isoxaben
Kathleen A Vermeersch et al.
PloS one, 10(2), e0118262-e0118262 (2015-02-18)
Recently, multicellular spheroids were isolated from a well-established epithelial ovarian cancer cell line, OVCAR-3, and were propagated in vitro. These spheroid-derived cells displayed numerous hallmarks of cancer stem cells, which are chemo- and radioresistant cells thought to be a significant
Devin H Currie et al.
BMC systems biology, 9, 30-30 (2015-06-27)
Thermoanaerobacterium saccharolyticum is a hemicellulose-degrading thermophilic anaerobe that was previously engineered to produce ethanol at high yield. A major project was undertaken to develop this organism into an industrial biocatalyst, but the lack of genome information and resources were recognized
Thomas B Kakule et al.
Journal of the American Chemical Society, 136(51), 17882-17890 (2014-12-02)
The programming of the fungal polyketide synthase (PKS) is quite complex, with a simple domain architecture leading to elaborate products. An additional level of complexity has been found within PKS-based pathways where the PKS is fused to a single module
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