423602

Ethyl cis-3-iodoacrylate

98%

• Lineární vzorec: ICH=CHCO₂C₂H₅
• Číslo CAS: 31930-36-6
• Molekulová hmotnost: 226.01
• NACRES: NA.22
• PubChem Substance ID: 24866512
• UNSPSC Code: 12352100
• MDL number: MFCD00209584
• Assay: 98%
• Form: liquid

Vlastnosti

• Quality Segment: 200
• assay: 98%
• form: liquid
• refractive index: n20/D 1.533 (lit.)
• bp: 85 °C/20 mmHg (lit.)
• density: 1.765 g/mL at 25 °C (lit.)
• functional group: ester, iodo
• storage temp.: 2-8°C
• SMILES string: [H]\C(I)=C(/[H])C(=O)OCC
• InChI: 1S/C5H7IO2/c1-2-8-5(7)3-4-6/h3-4H,2H2,1H3/b4-3-
• InChI key: AELYFQSZXFFNGP-ARJAWSKDSA-N

Popis

General description

Ethyl cis-3-iodoacrylate (cis-ethyl-β-iodoacrylate, ethyl (Z)-β-iodoacrylate) is Z-vinyl iodide derivative. It is reported to be prepared from ethyl propiolate by treating with sodium iodide. Its Suzuki coupling reaction with cyclic vinyl boronic acids has been studied.

Application

Ethyl cis-3-iodoacrylate may be used in the synthesis of the following:

• vinyl sulfides
• (Z)-1-iodohept-1-en-3-ol
• (E)-1-iodohept-1-en-3-ol
• (Z)-β-iodoacrolein
• 6-oxo-M₁Guo

Bezpečnostní informace

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Skladovací třída: 10 - Combustible liquids
• wgk: WGK 3
• flash_point_f: 210.2 °F - closed cup
• flash_point_c: 99 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter