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267317

Sigma-Aldrich

Rhenium

foil, thickness 0.25 mm, 99.98% trace metals basis

Synonym(s):

Rhenium element

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About This Item

Empirical Formula (Hill Notation):
Re
CAS Number:
7440-15-5
Molecular Weight:
186.21
MDL number:
MFCD00011195
UNSPSC Code:
12141737
PubChem Substance ID:
24856216
NACRES:
NA.23

Assay

99.98% trace metals basis

form

foil

description

19.3 μΩ-cm, 20°C

thickness

0.25 mm

bp

5596 °C (lit.)
5627 °C (lit.)

mp

3180 °C (lit.)

density

21.02 g/cm3 (lit.)

SMILES string

[ReH]

InChI

1S/Re

InChI key

WUAPFZMCVAUBPE-UHFFFAOYSA-N

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General description

Rhenium is a very hard, corrosion, and wear-resistant rare metal with ahigh atomic number. It is widely used in the field of catalysis and the preparationof alloys for jet engines.

Application

Rhenium can be used as a working electrode for electrochemical hydrogen evolution reactions.

It can be used as an additive to prepare a molybdenum-titanium-zirconium (TZM) alloy joint to improve its tensile strength.

It can also be used as a catalyst for various hydrodeoxygenation reactions.

Quantity

3.3 g = 25 × 25 mm; 13.2 g = 50 × 50 mm

Storage Class Code

13 - Non Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Titel Jurca et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(13), 4278-4286 (2013-02-02)
The development of rhenium(I) chemistry has been restricted by the limited structural and electronic variability of the common pseudo-octahedral products fac-[ReX(CO)3L2] (L2 = α-diimine). We address this constraint by first preparing the bidentate bis(imino)pyridine complexes [(2,6-{2,6-Me2C6H3N=CPh}2C5H3N)Re(CO)3X] (X = Cl 2
Ties J Korstanje et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(39), 13224-13234 (2013-08-16)
Rhenium-based complexes are powerful catalysts for the dehydration of various alcohols to the corresponding olefins. Here, we report on both experimental and theoretical (DFT) studies into the mechanism of the rhenium-catalyzed dehydration of alcohols to olefins in general, and the
Wilber Quispe-Tintaya et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(21), 8668-8673 (2013-04-24)
No significant improvement in therapy of pancreatic cancer has been reported over the last 25 y, underscoring the urgent need for new alternative therapies. Here, we coupled a radioisotope, (188)Rhenium, to an attenuated (at) live Listeria monocytogenes (Listeria(at)) using Listeria-binding
Jonathan M Smieja et al.
Inorganic chemistry, 52(5), 2484-2491 (2013-02-20)
Electrocatalytic properties, X-ray crystallographic studies, and infrared spectroelectrochemistry (IR-SEC) of Mn(bpy-tBu)(CO)3Br and [Mn(bpy-tBu)(CO)3(MeCN)](OTf) are reported. Addition of Brönsted acids to CO2-saturated solutions of these Mn complexes and subsequent reduction of the complexes lead to the stable and efficient production of
Raphael Horvath et al.
Inorganic chemistry, 52(3), 1304-1317 (2013-01-15)
Transition-metal complexes of the types [Re(CO)(3)Cl(NN)], [Re(CO)(3)py(NN)](+), and [Cu(PPh(3))(2)(NN)](+), where NN = 4,4'-bis(5-phenyl-1,3,4-oxadiazol-2-yl)-2,2'-bipyridine (OX) and 4,4'-bis(N,N-diphenyl-4-[ethen-1-yl]-aniline)-2,2'-bipyridine (DPA), have been synthesized and characterized. Crystal structures for [Re(CO)(3)Cl(DPA)] and [Cu(PPh(3))(2)(OX)]BF(4) are presented. The crystal structure of the rhenium complex shows a trans
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