683086

[Ir(cod)(acac)]

Umicore

• Synonym(s): (Acetylacetonato)(1,5-cyclooctadiene)iridium(I), Acetylacetonato(1,5-cyclooctadiene)iridium(I), Ir(acac)(COD)
• Empirical Formula (Hill Notation): C₁₃H₁₉IrO₂
• CAS Number: 12154-84-6
• Molecular Weight: 399.51
• MDL number: MFCD08273779
• UNSPSC Code: 12161600
• PubChem Substance ID: 329760791
• NACRES: NA.22

Properties

• form: crystals
• reaction suitability: core: iridium; reagent type: catalyst
• mp: 150-155 °C (dec.)
• SMILES string: CC(=O)\C=C(\C)O[Ir].C1CC=CCCC=C1
• InChI: 1S/C8H12.C5H8O2.Ir/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3,6H,1-2H3;/q;;+1/p-1/b2-1-,8-7-;4-3-;
• InChI key: JHNBKYKCHXHKET-DWVXZKBMSA-M

Description

Application

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Precursor for Iridium complexes and catalysts

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves