Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

795712

Sigma-Aldrich

Molybdenum tris(1,2-bis(trifluoromethyl)ethane-1,2-dithiolene)

Synonym(s):

Mo(tfd)3

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C12F18MoS6
CAS Number:
1494-07-1
Molecular Weight:
774.43
UNSPSC Code:
12352103
PubChem Substance ID:
329768505

form

solid

SMILES string

FC(F)(F)C(S1)=C(C(F)(F)F)S[Mo]213(SC(C(F)(F)F)=C(C(F)(F)F)S3)SC(C(F)(F)F)=C(C(F)(F)F)S2

InChI

1S/3C4H2F6S2.Mo/c3*5-3(6,7)1(11)2(12)4(8,9)10;/h3*11-12H;/q;;;+6/p-6/b3*2-1-;

InChI key

KPELOYUGUICPOT-JVUUZWNBSA-H

General description

The p dopant Mo(tfd)3 has high electron affinity (EA= 5.6 eV).The efficiency of Mo(tfd)3 as a dopant has been studied extensively by ultraviolet and X ray photoelectron spectroscopy, Rutherford backscattering, etc.

Application

Molybdenum tris(1,2-bis(trifluoromethyl)ethane-1,2-dithiolene) (Mo(tfd)3) may be used to p dope the hole transporting layer of HTM N,N′-di[(1-naphthyl)-N,N′-diphenyl]-1,1′-biphenyl-4,4′- diamine.
It may be used as a dopant to reduced contact resistance in pentacene based organic field effect transistors (OFETs).

Biochem/physiol Actions

p-dopant

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

A molybdenum dithiolene complex as p-dopant for hole-transport materials: A multitechnique experimental and theoretical investigation.
Qi Y, et al.
Chemistry of Materials, 524-531 null
A molybdenum dithiolene complex as p-dopant for hole-transport materials: A multitechnique experimental and theoretical investigation.
Qi Y, et al.
Chemistry of Materials null
Pentacene organic field-effect transistors with doped electrode-semiconductor contacts
Tiwari, S. P.;
Organic Electronics, 11, 860-860 (2010)
Remote doping of a pentacene transistor: Control of charge transfer by molecular-level engineering
Zhao W, et al.
Applied Physics Letters, 12 null
Use of a high electron-affinity molybdenum dithiolene complex to p-dope hole-transport layers.
Qi Y, et al.
Journal of the American Chemical Society null
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service