Skip to Content
Merck
All Photos(3)

Key Documents

View All Documentation

383074

Sigma-Aldrich

Bismuth(III) nitrate pentahydrate

ACS reagent, ≥98.0%

Sign Into View Organizational & Contract Pricing
All Photos(3)

About This Item

Linear Formula:
Bi(NO3)3 · 5H2O
CAS Number:
10035-06-0
Molecular Weight:
485.07
EC Number:
233-791-8
UNSPSC Code:
12352302
PubChem Substance ID:
24863932
NACRES:
NB.24

grade

ACS reagent

Assay

≥98.0%

form

(Powder or Crystals or Solid or Chunks)

reaction suitability

reagent type: catalyst
core: bismuth

impurities

≤0.005% insolubles

bp

75-80 °C (lit.)

mp

30 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.005%

cation traces

Ag: ≤0.001%
As: ≤0.001%
Ca: ≤0.005%
Cu: ≤0.002%
Fe: ≤0.001%
K: ≤0.01%
Na: ≤0.02%
Pb: ≤0.002%

SMILES string

O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C

InChI

1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1

InChI key

DPLOIMSBRDLLRI-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Bismuth(III) nitrate pentahydrate is a non-toxic, inexpensive, easy to handle and air insensitive reagent, commonly used in organic synthesis with a wide range of applications.

Application

Bismuth(III) nitrate pentahydrate may be used in the following processes:
  • Conversion of thioamides and thioureas to their oxo derivatives.
  • Transformation of aromatic aldehydes to carboxylic acids under microwave and solvent free conditions.
  • Synthesize coumarins by Pechmann condensation under solvent free conditions.
  • As a precursor in the synthesis of pure and lanthanum-modified bismuth ferrite (BFO) ceramics.
  • As a nitrating agent in the synthesis of methyl nitramino-2,4,6-trinitrobenzenes under microwave irradiation.
  • As a catalyst in the preparation of 4-amino-5-pyrimidine carbonitrile and pyrimidinone derivatives.
  • Synthesis of glycosides by Fischer glycosylation of unprotected sugars.
  • Synthesis of bismuth oxide (Bi2O3) nanoparticles.
  • Oxidation of 4-substituted Hantzsch 1,4-dihydropyridines.
  • Selective oxidation of sufides to sulfoxides.

Pictograms

Flame over circleCorrosion
GHS03,GHS05

Signal Word

Danger

Hazard Statements

H272,H318

Hazard Classifications

Eye Dam. 1 - Ox. Sol. 2

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Bismuth (III) nitrate pentahydrate: a convenient and selective reagent for conversion of thiocarbonyls to their carbonyl compounds.
Mohammadpoor-Baltork I, et al.
Tetrahedron Letters, 44(3), 591-594 (2003)
Bismuth Nitrate Pentahydrate: A Convenient Reagent for the Oxidation of Hantzsch 1,4-Dihydropyridines.
Mashraqui SH and Karnik MA.
Synthesis, 1998(5), 713-714 (1998)
Preparation of lead-free nanoglass frit powder for crystalline silicon solar cells.
Che Q, et al.
Applied Energy, 112, 657-662 (2013)
Bismuth (III) nitrate pentahydrate: a stoichiometric reagent for microwave induced mild and highly efficient aerial oxidation of aromatic aldehydes under solvent-free conditions.
Mukhopadhyay C and Datta A.
Catalysis Communications, 9(15), 2588-2592 (2008)
Facile synthesis of bismuth oxide nanoparticles by a hydrolysis solvothermal route and their visible light photocatalytic activity.
Luan X, et al.
Environmental Engineering and Management Journal, 14(3), 703-707 (2015)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service