709042

CX31

Umicore, 95%

• Synonym(s): Chlorophenylallyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]palladium (II), [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloro[3-phenylallyl]palladium(II)
• Empirical Formula (Hill Notation): C₃₆H₄₅ClN₂Pd
• CAS Number: 884879-23-6
• Molecular Weight: 647.63
• MDL number: MFCD11045095
• UNSPSC Code: 12161600
• PubChem Substance ID: 329762845
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 95%
• form: powder
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 205-208 °C
• SMILES string: [CH2][CH][CH]c1ccccc1.CC(C)c2cccc(C(C)C)c2N3C=CN(\C3=[Pd]/Cl)c4c(cccc4C(C)C)C(C)C
• InChI: 1S/C27H36N2.C9H9.ClH.Pd/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;1-2-6-9-7-4-3-5-8-9;;/h9-16,18-21H,1-8H3;2-8H,1H2;1H;/q;;;+1/p-1
• InChI key: RWGNZUQSYXTZIX-UHFFFAOYSA-M

Description

Application

• Catalyst for Suzuki coupling (eq. 1)
• Catalyst for Buchwald-Hartwig amination reaction (eq. 2)

Catalyst for:

• Suzuki-Miyaura couplings
• Buchwald-Hartwig couplings

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H302 + H312 + H332,H315,H319
• Precautionary Statements: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves