215112
Phosphorous acid
99%
Synonym(s):
Phosphonic acid
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All Photos(5)
About This Item
Empirical Formula (Hill Notation):
H3O3P
CAS Number:
Molecular Weight:
82.00
EC Number:
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.21
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Quality Level
Assay
99%
form
crystals or chunks
flakes
solubility
water: soluble
density
1.651 g/mL at 25 °C (lit.)
SMILES string
[H]P(O)(O)=O
InChI
1S/H3O3P/c1-4(2)3/h4H,(H2,1,2,3)
InChI key
ABLZXFCXXLZCGV-UHFFFAOYSA-N
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General description
Phosphorous acid (or phosphonic acid) is a phosphorus oxoacid commonly used as an intermediate in chemical synthesis for the production of various phosphorus compounds. It is also used as a strong reducing agent in organic synthesis.
Application
Phosphorous acid (H3PO3, orthophosphorous acid) may be used as one of the reaction components for the synthesis of the following:
- α-aminomethylphosphonic acids via Mannich-Type Multicomponent Reaction
- 1-aminoalkanephosphonic acids via amidoalkylation followed by hydrolysis
- N-protected α-aminophosphonic acids (phospho-isosteres of natural amino acids) via amidoalkylation reaction
Signal Word
Danger
Hazard Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Amidoalkylation of phosphorous acid.
Vinyukov AV, et al.
Russ. J. Gen. Chem., 85(2), 366-369 (2015)
Marina Borges Osorio et al.
Plant physiology, 181(1), 332-352 (2019-07-03)
Phosphorus (P) is an essential macronutrient for all living organisms and limits plant growth. Four proteins comprising a single SYG1/Pho81/XPR1 (SPX) domain, SPX1 to SPX4, are putative phosphate-dependent inhibitors of Arabidopsis (Arabidopsis thaliana) PHOSPHATE STARVATION RESPONSE1 (PHR1), the master transcriptional
Abraham Vega et al.
Langmuir : the ACS journal of surfaces and colloids, 28(21), 8046-8051 (2012-05-05)
Phosphonic acid monolayers are being considered as versatile surface modification agents due to their unique ability to attach to surfaces in different configurations, including mono-, bi-, or even tridentate arrangements. Tethering by aggregation and growth (T-BAG) of octadecylphosphonic acid (ODPA)
Yunjun Guo et al.
Bioconjugate chemistry, 23(7), 1470-1477 (2012-06-06)
Somatostatin receptors (SSTr) are overexpressed in a wide range of neuroendocrine tumors, making them excellent targets for nuclear imaging and therapy, and radiolabeled somatostatin analogues have been investigated for positron emission tomography imaging and radionuclide therapy of SSTr-positive tumors, especially
Faizah Md Yasin et al.
Chemical communications (Cambridge, England), 48(81), 10102-10104 (2012-09-08)
Size selective growth of palladium nano-particles 2-7 nm in diameter on the surface of carbon nano-onions (CNOs) (derived from catalytic cracking of methane) in water involves pretreating the CNOs with p-phosphonic acid calix[8]arene then H(2)PdCl(4) followed by dynamic thin film
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