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217905

Sigma-Aldrich

Copper(II) fluoride

98%

Synonym(s):

Cupric fluoride

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About This Item

Empirical Formula (Hill Notation):
CuF2
CAS Number:
7789-19-7
Molecular Weight:
101.54
EC Number:
232-147-3
MDL number:
MFCD00010977
UNSPSC Code:
12352302
PubChem Substance ID:
24853038
NACRES:
NA.23

Quality Level

100

Assay

98%

form

powder

loss

<0.5% loss on drying, 105 °C, 1h

mp

950 °C (dec.) (lit.)

density

4.23 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

F[Cu]F

InChI

1S/Cu.2FH/h;2*1H/q+2;;/p-2

InChI key

GWFAVIIMQDUCRA-UHFFFAOYSA-L

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General description

Copper fluoride is a monoclinic weak ferromagnet. The structural properties were investigated by neutron diffraction.

Application

Copper fluoride can act as an intermediate in the green synthesis of fluoro aromatics.

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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J G de Oliveira Cordeiro
The Bulletin of Tokyo Medical and Dental University, 42(3), 105-116 (1995-12-01)
The aim of this investigation was to evaluate the effect of topical applications of various fluoride compounds on the development of root surface caries in hamsters. Male golden hamsters (n = 115) were divided into 7 groups and were given
M Maltz et al.
Scandinavian journal of dental research, 96(5), 390-392 (1988-10-01)
Topical applications of 10 mM CuF2, 10 mM CuSO4, or 20 mM NaF solutions were performed twice a day in hamsters infected with S. mutans and maintained on a high sucrose diet. Animals receiving the copper compounds exhibited lower plaque
"A greener" synthetic route for fluoroaromatics via copper (II) fluoride.
Subramanian MA and Manzer LE
Science, 297(5587), 1665-1665 (2002)
Magnetic and crystal structure of copper(II) fluoride
Fischer P, et al.
Journal of Physics and Chemistry of Solids, 35(12), 1683-1689 (1974)
Kounosuke Oisaki et al.
Journal of the American Chemical Society, 128(22), 7164-7165 (2006-06-01)
An enantioselective aldol reaction between ketones and ketene silyl acetals is described using CuF-chiral phosphine as a catalyst. The key for high enantioselectivity was the development of a novel ligand derived from Taniaphos combined with the unique accelerative effect of
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