328812
Acetoacetamide
97%
Synonym(s):
α-Acetylacetamide, 3-Oxobutanamide, 3-Oxobutyramide, Acetoacetic acid amide, Acetylacetamide
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About This Item
Linear Formula:
CH3COCH2CONH2
CAS Number:
Molecular Weight:
101.10
Beilstein:
1560550
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
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Assay
97%
mp
53-56 °C (lit.)
solubility
water: soluble 1 g/10 mL, clear, colorless
functional group
amide
ketone
SMILES string
CC(=O)CC(N)=O
InChI
1S/C4H7NO2/c1-3(6)2-4(5)7/h2H2,1H3,(H2,5,7)
InChI key
GCPWJFKTWGFEHH-UHFFFAOYSA-N
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General description
Acetoacetamide is a degradation product of acesulfame-K, sweetener. Acetoacetamide undergoes alkaline hydrolysis to form salt of acetoacetic acid.
Application
Acetoacetamide was used in a study to assess the stability of artificial sweeteners- aspartame, acesulfame-K and binary sweetener blend of aspartame x acesulfame-K during storage. Acetoacetamide was also used in analysis of multiple sweeteners and their degradation products in lassi by HPLC.
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point(F)
235.4 °F - closed cup
Flash Point(C)
113 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A Simple Method For The Preparation Of Acetoacetate.
Lopez-Soriano FJ and Argiles JM.
Analytical Letters, 18(5), 589-592 (1985)
V George et al.
Journal of food science and technology, 47(4), 408-413 (2010-08-01)
A solid phase extraction method using C18 cartridges was standardized for the isolation of multiple sweeteners (aspartame, acesulfame-K and saccharin) and their degradation products (diketopiperazine, Lphenylalanine, acetoacetamide and 2-sulfobenzoic acid) from lassi. Analytical conditions for HPLC were standardized over C18
Assessment of stability of binary sweetener blend (aspartame x acesulfame-K) during storage in whey lemon beverage.
Arora S, et al.
Journal of Food Science and Technology, 50(4), 1-7 (2011)
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