497312
4-Piperidinemethanol
97%
Synonym(s):
4-(Hydroxymethyl)piperidine
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About This Item
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Quality Level
Assay
97%
bp
118-120 °C/10 mmHg (lit.)
mp
55-59 °C (lit.)
SMILES string
OCC1CCNCC1
InChI
1S/C6H13NO/c8-5-6-1-3-7-4-2-6/h6-8H,1-5H2
InChI key
XBXHCBLBYQEYTI-UHFFFAOYSA-N
Related Categories
General description
4-Piperidinemethanol is a cyclic secondary amine. Its standard molar enthalpies of combustion, sublimation and formation have been determined.
Application
4-Piperidinemethanol may be used in the preparation of:
- N-tert-butoxycarbonyl-4-hydroxymethyl piperidine
- desferrioxamine B (DFO) containing third generation triazine dendrimer
- ethyl 3-(4-(hydroxymethyl)piperidin-1-yl)propanoate (EHMPP)
- 4-(hydroxymethyl)piperidine-1-carbodithioic acid (HL)
- 1-[[(1E)-2-(4-chlorophenyl)ethenyl]sulfonyl]-4-piperidinemethanol
Substrate used in solid-phase organic synthesis of a secondary amine.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
230.0 °F - closed cup
Flash Point(C)
110 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Bioorganic & medicinal chemistry, 18(15), 5749-5753 (2010-07-10)
The synthesis of a third generation triazine dendrimer, 1, containing multiple, iron-sequestering desferrioxamine B (DFO) groups is described. Benzoylation of the hydroxamic acid groups of DFO and formation of a reactive dichlorotriazine provide the intermediate for reaction with the second
Synthesis, spectroscopy, and biological activity of heterobimetallic complexes containing Sn (IV) and Pd (II) with 4-(hydroxymethyl) piperidine-1-carbodithioic acid.
Russ. J. Gen. Chem., 83(12), 2380-2385 (2013)
Organic letters, 6(12), 1935-1938 (2004-06-05)
[reaction: see text] An expedient solid-phase synthetic approach to secondary and tertiary amines was developed. The protocol employs conversion of resin-bound amino alcohols to the corresponding iodides, followed by iodide displacement with primary or secondary amines or with unprotected amino
Standard molar enthalpies of formation of 2-, 3-, and 4-piperidinomethanol isomers.
The Journal of Chemical Thermodynamics, 38(8), 1008-1012 (2006)
Synthesis and evaluation of 1-arylsulfonyl-3-piperazinone derivatives as factor Xa inhibitor.
Chemical & Pharmaceutical Bulletin, 49(10), 1237-1244 (2001)
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