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746428

Sigma-Aldrich

Potassium iodide

anhydrous, free-flowing, Redi-Dri, ACS reagent, ≥99%

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About This Item

Linear Formula:
KI
CAS Number:
Molecular Weight:
166.00
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent
anhydrous

Quality Level

vapor pressure

1 mmHg ( 745 °C)

product line

Redi-Dri

Assay

≥99%

form

crystals

quality

free-flowing

impurities

≤0.001% N compounds
≤0.005% insolubles

loss

≤0.2% loss on drying

pH

6.0-9.2 (25 °C, 5%)

mp

681 °C (lit.)

anion traces

chloride, bromide (as Cl)-: ≤0.01%
iodate (IO3-): ≤3 ppm
phosphate (PO43-): ≤0.001%
sulfate (SO42-): ≤0.005%

cation traces

Ba: ≤0.002%
Ca: ≤0.002%
Fe: ≤3 ppm
Mg: ≤0.001%
Na: ≤0.005%
heavy metals (as Pb): ≤5 ppm

SMILES string

[K+].[I-]

InChI

1S/HI.K/h1H;/q;+1/p-1

InChI key

NLKNQRATVPKPDG-UHFFFAOYSA-M

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General description

Potassium iodide is a water soluble inorganic salt that can be prepared by reacting hydrogen iodide and potassium bicarbonate.

Redi-Dri technology eliminates clumping and the need for complicated procedures to keep your salts free-flowing. Keeping your salts dry helps improve your results by giving accurate measurements and easier-to-handle salts and buffers. Rather than drying your salts in an oven or desiccator or breaking them apart manually, Redi-Dri ensures that your salts will remain easy-to-use for months without worrying about anti-caking agents. Even after repeated openings you can be assured that your results are always accurate. Redi-Dri saves you time, energy and money by keeping your salts usable for longer!

Application

Potassium iodide may be used as a catalyst in the following processes:
  • Conversion of aromatic primary amines to the corresponding nitro compounds in the presence of tert-butyl hydroperoxide as oxidant.
  • Conversion of aryl halide to aryl iodides in the presence of nickel catalysts.
  • Preparation of sulfonated oxindoles from activated alkenes and sulfonylhydrazides in water and in the presence of 8-crown-6 and tert-butyl hydroperoxide.

Features and Benefits

  • Increased efficiency – Eliminate time and effort of loosening hardened powders
  • Safety – Avoid risks of using tools of force to break up clumps
  • Economy – Faster preparation and solvation increase productivity and reduce costs
  • Assured quality – Excellent, expert-tested quality with no anti-caking agents
  • Flexible volumes – Available from research amounts to scale-up quantities

Legal Information

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Pictograms

Health hazard

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

STOT RE 1 Oral

Target Organs

Thyroid

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Articles

Redi-Dri™ prevents hygroscopic powders, such as inorganic salts, from absorbing moisture and forming clumps, leaving the salts free-flowing every time.

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