Skip to Content
Merck
All Photos(1)

Key Documents

458139

Sigma-Aldrich

tert-Butyl hydroperoxide solution

70 wt. % in H2O

Synonym(s):

TBHP, 1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
(CH3)3COOH
CAS Number:
Molecular Weight:
90.12
Beilstein:
1098280
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

form

liquid

Quality Level

reaction suitability

reaction type: C-H Activation
reagent type: catalyst
reagent type: oxidant

concentration

12.25-13.31% (active oxygen)
69.0-75.0% (Na2S2O3, titration)
70 wt. % in H2O

refractive index

n20/D 1.386

pH

4.3

bp

96.2 °C

density

0.93 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

InChI key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Application

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts
Versatile reagent for oxidations.

Legal Information

Product of Arkema Inc.

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 3

Flash Point(F)

107.6 °F - closed cup

Flash Point(C)

42 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 1

1 of 1

J. Chem. Res. Synop., 7, 390-394 (2003)
J. Catal., 224, 288-296 (2004)
Sci. Synth., 3, 91-131 (2004)
Inorgorganica Chimica Acta, 357, 2237-2244 (2004)
Ferroptosis suppressed the growth of melanoma that may be related to DNA damage.
Zhenying Wang et al.
Dermatologic therapy, 32(4), e12921-e12921 (2019-04-13)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service