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63409

Sigma-Aldrich

Sodium malonate dibasic

≥97.0% (NT)

Synonym(s):

Disodium malonate, Malonic acid disodium salt

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About This Item

Linear Formula:
CH2(COONa)2
CAS Number:
Molecular Weight:
148.03
Beilstein:
3917013
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

≥97.0% (NT)

form

solid

SMILES string

[Na+].[Na+].[O-]C(=O)CC([O-])=O

InChI

1S/C3H4O4.2Na/c4-2(5)1-3(6)7;;/h1H2,(H,4,5)(H,6,7);;/q;2*+1/p-2

InChI key

PRWXGRGLHYDWPS-UHFFFAOYSA-L

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Application

Sodium malonate dibasic can be use in the synthesis of sodium carbonate and sodium oxalate via wet oxidation and catalytic wet oxidation. It can also be used to synthesize malonato-bridged manganese(II)complexes like [Mn(mal)(H2O)2]n and [Mn2(mal)2(4,4′-bipy)(H2O)2]n,(bipy =bipyridine, mal =malonate), which have the tendency to show weak anti-ferromagnetic effect.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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"Magneto- structural correlations in 2D and 3D extended structures of manganese (II)- malonate systems"
Maji KT, et al.
Inorganic Chemistry, 42(03), 709-716 (2003)
"Selective organic removal from the alumina industrial liquor: Wet oxidation and catalytic wet oxidation of disodium malonate"
Eyer S , et al.
Industrial & Engineering Chemistry Research, 41(05), 1166-1170 (2002)
Waree Limwikrant et al.
International journal of pharmaceutics, 431(1-2), 237-240 (2012-04-28)
A new 2/1 carbamazepine (CBZ)/malonic acid (MA) cocrystal polymorph form C was formed using a vibrational rod mill, whereas the known cocrystal polymorph form A was prepared using a ball mill. IR measurements showed that the interaction between CBZ and
Damien L Callahan et al.
Phytochemistry, 81, 80-89 (2012-07-17)
Leaf material from nine Ni hyperaccumulating species was collected in New Caledonia: Homalium kanaliense (Vieill.) Briq., Casearia silvana Schltr, Geissois hirsuta Brongn. & Gris, Hybanthus austrocaledonicus Seem, Psychotria douarrei (G. Beauvis.) Däniker, Pycnandra acuminata (Pierre ex Baill.) Swenson & Munzinger
Arturo Orellana et al.
The Journal of organic chemistry, 77(12), 5286-5296 (2012-05-04)
An efficient synthesis of (-)-kainic acid, through a high-pressure-promoted Diels-Alder cycloaddition of a vinylogous malonate derived from 4-hydroxyproline, is described. The bicyclic adduct could be converted into the natural product with complete stereocontrol.

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