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Sigma-Aldrich

Poly(diallyldimethylammonium chloride) solution

average Mw <100,000 (very low molecular weight), 35 wt. % in H2O

Synonym(s):

PDADMAC

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About This Item

Linear Formula:
(C8H16ClN)n
CAS Number:
MDL number:
UNSPSC Code:
12162002
NACRES:
NA.23

mol wt

average Mw <100,000 (very low molecular weight)

concentration

35 wt. % in H2O

refractive index

n20/D 1.417

viscosity

100-200 cP(25 °C)

density

1.09 g/mL at 25 °C

InChI

1S/C8H16N.ClH/c1-5-7-9(3,4)8-6-2;/h5-6H,1-2,7-8H2,3-4H3;1H/q+1;/p-1

InChI key

GQOKIYDTHHZSCJ-UHFFFAOYSA-M

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General description

Poly(diallyldimethylammonium chloride) (PDDA) is a cationicpolyelectrolyte that easily ionizes when dissolved in water. This polymer iswidely used in the fields of waste-water treatment (as a flocculant) and the functionalizationof nanoparticles.

Application

Poly(diallyldimethylammonium chloride) can be used as a stabilizing agent in the synthesis of nanoparticles such as capped copper hexacyanoferrate (CuHCF) nanoparticles. The addition of PDDA protects the particles from aggregation and allows the synthesis of nanoparticles with controlled size and polydispersity. It can also be used to fabricate chemical and biological sensors. For example, PDDA-modified catalyst platforms can be used in the electrochemical detection of L-cysteine.

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

>212.0 °F - closed cup

Flash Point(C)

> 100 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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The p-type MoS2 nanocube modified poly(diallyl dimethyl ammonium chloride)-mesoporous carbon composites as a catalytic amplification platform for electrochemical detection of l-cysteine
Zhixiang Zheng, et al.
Sensors and Actuators B, Chemical, 221, 1162-1169 (2015)
Synthesis of poly(diallyldimethylammonium) capped copper hexacyanoferrate (CuHCF) nanoparticles: An efficient stabiliser for Pickering emulsions
Martin Mayer, et al.
Journal of Colloid and Interface Science, 505, 364-372 (2017)
Shangzhi Chen et al.
Nature nanotechnology, 15(1), 35-40 (2019-12-11)
Being able to dynamically shape light at the nanoscale is one of the ultimate goals in nano-optics1. Resonant light-matter interaction can be achieved using conventional plasmonics based on metal nanostructures, but their tunability is highly limited due to a fixed
Lulu Han et al.
Biomaterials, 34(4), 975-984 (2012-11-07)
The directional cell migration plays a crucial role in a variety of physiological and pathological processes. It can be controlled by the gradient cues immobilized on the substrate. The poly(sodium 4-styrenesulfonate) (PSS)/poly(diallyldimethylammonium) chloride (PDADMAC) multilayers were post-treated in a gradient
Lokesh S Koodlur
Bioelectrochemistry (Amsterdam, Netherlands), 91, 21-27 (2013-01-22)
A self-assembled molecular film of a water-soluble cobalt tetrasulfophthalocyanine was deposited on a gold substrate premodified with poly(diallyldimethylammonium chloride). The process of layer-by-layer assembly on the gold substrate was characterized using UV-Vis, Raman spectroscopy, ellipsometry, contact angle measurements, atomic force

Articles

Recently, layer-by-layer (LbL) assembly has emerged as a versatile, gentle and, simple method for immobilization of functional molecules in an easily controllable thin film morphology.1,2 In this short review, we introduce recent advances in functional systems fabricated by using the mild, yet adaptable LbL technique.

We present an article that discusses two applications in particular; first, using these layers as polyelectrolyte membranes to control permeability.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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