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398802

Sigma-Aldrich

Tetra(ethylene glycol) diacrylate

technical grade, cross-linking reagent polymerization reactions, acrylate, 100-150 ppm HQ as inhibitor, 150-200 ppm MEHQ as inhibitor

Synonym(s):

TTEGDA

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About This Item

Linear Formula:
(H2C=CHCO2CH2CH2OCH2CH2)2O
CAS Number:
Molecular Weight:
302.32
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

product name

Tetra(ethylene glycol) diacrylate, technical grade, contains 100-150 ppm HQ as inhibitor, 150-200 ppm MEHQ as inhibitor

grade

technical grade

form

liquid

contains

100-150 ppm HQ as inhibitor
150-200 ppm MEHQ as inhibitor

reaction suitability

reagent type: cross-linking reagent
reaction type: Polymerization Reactions

refractive index

n20/D 1.465 (lit.)

density

1.11 g/mL at 25 °C (lit.)

Ω-end

acrylate

α-end

acrylate

polymer architecture

shape: linear
functionality: homobifunctional

SMILES string

C=CC(=O)OCCOCCOCCOCCOC(=O)C=C

InChI

1S/C14H22O7/c1-3-13(15)20-11-9-18-7-5-17-6-8-19-10-12-21-14(16)4-2/h3-4H,1-2,5-12H2

InChI key

HCLJOFJIQIJXHS-UHFFFAOYSA-N

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General description

Tetra(ethylene glycol) diacrylate is a long-chain hydrophilic, crosslinking monomer widely used in the preparation of gel polymer electrolytes for Li-ion polymer batteries, acrylic polymers, and coating materials.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Skin Sens. 1

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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J R Nethercott et al.
Journal of occupational medicine. : official publication of the Industrial Medical Association, 26(7), 513-516 (1984-07-01)
A woman who worked as a materials handler in a plant manufacturing acrylated chemicals developed allergic contact allergy to tetraethylene glycol diacrylate (TTEGDA). Four co-workers experienced skin irritation 12 to 36 hours after skin contact with TTEGDA but had no
Tetraethylene glycol diacrylate.
American Industrial Hygiene Association journal, 42(11), B49-B50 (1981-11-01)
Ye Ji Son et al.
Polymers, 12(4) (2020-04-30)
The effect of crosslinking on vapor permeation behavior of polyelectrolyte membranes was studied. Poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (PAMPS) membranes were crosslinked by using crosslinkers with different lengths between the reactive ends. Crosslinked membranes with a longer crosslinking length showed lower water vapor
Sean Brahim et al.
Biomacromolecules, 4(3), 497-503 (2003-05-14)
An amphiphilic hydrogel network was synthesized from a cross-linked poly(2-hydroxyethyl methacrylate) backbone copolymerized with the monomers 3-(trimethoxysilyl)propyl methacrylate (PMA) and dimethylaminoethyl methacrylate (DMAEMA) using tetraethylene glycol diacrylate (TEGDA) as cross-linker and using the radical initiator system comprising N,N,N',N'-tetramethylethylenediamine and ammonium
Synthesis of electron beam cured free-standing ion-gel membranes for organic electronics applications
Marco Mennillo, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 54, 2352-2360 (2016)

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