496367
6,6′-Dimethyl-2,2′-dipyridyl
98%
Synonym(s):
2-Methyl-6-(6-methylpyridin-2-yl)pyridine, 6,6′-Dimethyl-2,2′-bipyridine, 6,6′-Dimethyl-2,2′-bipyridyl
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Assay
98%
mp
93-95 °C (lit.)
SMILES string
Cc1cccc(n1)-c2cccc(C)n2
InChI
1S/C12H12N2/c1-9-5-3-7-11(13-9)12-8-4-6-10(2)14-12/h3-8H,1-2H3
InChI key
OHJPGUSXUGHOGE-UHFFFAOYSA-N
General description
6,6′-dimethyl-2,2′-bipyridyl (dmbp) also known as 6,6′-dimethyl-2,2′-bipyridine, is commonly used as a ligand to form complexes with ions such as Pd(II), Pt(II), Cu(II), Co(II) and Zn(II). The crystalline structure of dmbp has been investigated. Its synthesis from 6-bromopicoline has been reported.
Application
6,6′-dimethyl-2,2′-bipyridyl (6,6′-Dimethyl-2,2′-bipyridine)may be used in the synthesis of novel oligobipyridine ligands.
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Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Complexes of Pd(II), Pt(II), Cu(II), Co(II) and Zn(II) chlorides with 6,6'-dimethyl-2,2'-dipyridyl.
J. Inorg. Nucl. Chem., 43(7), 1529-1531 (1981)
Two convenient and high-yielding preparations of 6, 6'-dimethyl-2, 2'-bipyridine by homocoupling of 6-bromopicoline.
Tetrahedron Letters, 41(43), 8203-8206 (2000)
Spontaneous assembly of double-stranded helicates from oligobipyridine ligands and copper (I) cations: structure of an inorganic double helix.
Proceedings of the National Academy of Sciences of the USA, 84(9), 2565-2569 (1987)
6,6'-Dimethyl-2,2'-bipyridyl.
Acta Crystallographica Section C, Structural Chemistry, 54(5), 661-662 (1998)
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