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203440

Sigma-Aldrich

Indium(III) chloride

99.999% trace metals basis

Synonym(s):

Indium trichloride

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About This Item

Linear Formula:
InCl3
CAS Number:
Molecular Weight:
221.18
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99.999% trace metals basis

form

powder or flakes (or chunks)

reaction suitability

reagent type: catalyst
core: indium

impurities

≤15.0 ppm Trace Metal Analysis

density

3.46 g/mL at 25 °C (lit.)

SMILES string

Cl[In](Cl)Cl

InChI

1S/3ClH.In/h3*1H;/q;;;+3/p-3

InChI key

PSCMQHVBLHHWTO-UHFFFAOYSA-K

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General description

Indium(III) chloride is a Lewis acid catalystused in a variety of organic reactions. It also finds application in the fields of catalysis, solar cells, and optoelectronics.

Application

Indium(III) chloride can be used:
  • As a catalyst for the preparation of 1,3-dithiolanes from aldehydes and ketones.
  • For acylation of phenols, thiols, alcohols, and amines.
  • As a precursor to fabricate Indium tin oxide(ITO) thin films for dye-sensitized solar cells.
  • To prepare solution-processed oxide semiconductor thin-film transistors (OS TFTs) that can be used in display devices.

Pictograms

Health hazardCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C - STOT RE 1 Inhalation

Target Organs

Lungs

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

203440-50G:4548173313429
203440-10G:4548173313405
203440-VAR:
203440-1G:4548173313412
203440-BULK:


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Synthesis, 1712-1712 (2007)
Mecheril Valsan Nandakumar et al.
Chemical communications (Cambridge, England), (26), 2756-2758 (2007-06-28)
The indium-bipyridine-catalyzed, enantioselective ring-opening of meso-epoxides with aliphatic and aromatic thiols furnished 1,2-mercapto alcohols in good yields and excellent enantioselectivities; the crystal structure of the chiral catalyst reveals a pentagonal-bipyramidal coordination geometry around the indium center.
FTO/ITO double-layered transparent conductive oxide for dye-sensitized solar cells
Takuya Kawashima, et al.},
Journal of Photochemistry and Photobiology A: Chemistry, 164, 199-202 (2004)
Indium(III) chloride as an efficient, convenient catalyst for thioacetalization and its chemoselectivity
Sengodagounder Muthusamy, et al.
Tetrahedron Letters, 42, 359-362 (2001)
Tetrahedron Letters, 48, 6743-6743 (2007)

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