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Safety Information

229474

Sigma-Aldrich

Bismuth(III) iodide

≥99.998% trace metals basis

Synonym(s):

Bismuth triiodide, Triiodobismuthane

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About This Item

Empirical Formula (Hill Notation):
BiI3
CAS Number:
Molecular Weight:
589.69
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Assay:
≥99.998% trace metals basis
form:
powder and chunks

Quality Level

Assay

≥99.998% trace metals basis

form

powder and chunks

reaction suitability

reagent type: catalyst
core: bismuth

impurities

≤15.0 ppm Trace Metal Analysis

mp

408 °C (lit.)

density

5.78 g/mL at 25 °C (lit.)

SMILES string

I[Bi](I)I

InChI

1S/Bi.3HI/h;3*1H/q+3;;;/p-3

InChI key

KOECRLKKXSXCPB-UHFFFAOYSA-K

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Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

229474-VAR:
229474-10G:4548173986838
229474-100G:
229474-BULK:


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Mirko Scholz et al.
Physical chemistry chemical physics : PCCP, 20(16), 10677-10685 (2017-12-21)
Trivalent bismuth compounds featuring octahedral halide coordination, such as BiI3, double-perovskite structures and vacancy-ordered perovskite derivatives, have recently attracted considerable attention as potential environmentally benign thin film materials for solar light-harvesting and optoelectronic applications aiming to replace toxic lead-based perovskites.
Wenhua Bi et al.
Chemical communications (Cambridge, England), (44)(44), 5743-5745 (2008-11-15)
The dehydration of a iodobismuthate hybrid built up from Bi(4)I(16) clusters and protonated L-cystine molecules involves an unprecedented reversible dynamic structural change in the solid state leading to 1D BiI(4) chains and 1D helical molecular chains, highlighting the templating effect
Jie Sun et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 79(5), 904-908 (2011-05-10)
A novel series of Ge-Te-BiI(3) chalcogenide glasses were prepared by traditional melt-quenching method and the glass-forming region was determined. Properties measurements including density, Vis-NIR and infrared (IR) transmission spectra with FTIR, XRD, DSC were adopted to analyze the composition, structure
Minhua Su et al.
Journal of hazardous materials, 229-230, 72-82 (2012-06-20)
BiOI-MWCNT composites, with high absorption and visible-light photocatalytic performance, were synthesized by a solvothermal process, in which ethylene glycol (EG) participated in the reaction. Synthesized BiOI-MWCNT composites were characterized by X-ray diffraction (XRD), diffuse reflectance spectra (DRS), scanning electronic microscopy
Yang Chen et al.
Physical chemistry chemical physics : PCCP, 13(13), 5659-5667 (2011-02-12)
The solvothermal reactions of BiI(3), KI, I(2), 4,4'-bipyridine (4,4'-bipy), and a small amount of water in alcohol and acetonitrile produced four bipyridinium iodobismuthates {[MQ](3)[Bi(2)I(6)(μ-I)(3)][Bi(2)I(6)(μ-I)(2)(MQ)(2)](3)} (1, MQ(+) = N-methyl-4,4'-bipyridinium), {[EQ](3)[Bi(2)I(6)(μ-I)(3)][Bi(2)I(6)(μ-I)(2)(EQ)(2)](3)} (2, EQ(+) = N-ethyl-4,4'-bipyridinium), [MV][BiI(5)] (Eur. J. Inorg. Chem., 2010, 5326)

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