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235431

Sigma-Aldrich

Methyl-5-norbornene-2,3-dicarboxylic anhydride

90%

Synonym(s):

Methyl nadic anhydride

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About This Item

Empirical Formula (Hill Notation):
C10H10O3
CAS Number:
25134-21-8
Molecular Weight:
178.18
Beilstein:
162395
EC Number:
246-644-8
UNSPSC Code:
12352100
PubChem Substance ID:
24854104
NACRES:
NA.22

vapor density

6.1 (20 °C, vs air)

Quality Level

100

vapor pressure

5 mmHg ( 120 °C)

Assay

90%

form

liquid

refractive index

n20/D 1.506 (lit.)

density

1.232 g/mL at 25 °C (lit.)

SMILES string

[H][C@]12C3CC(C(C)=C3)[C@@]1([H])C(=O)OC2=O

InChI

1S/C10H10O3/c1-10-6-3-2-5(4-6)7(10)8(11)13-9(10)12/h2-3,5-7H,4H2,1H3/t5-,6+,7+,10+/m0/s1

InChI key

LTVUCOSIZFEASK-MPXCPUAZSA-N

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Application

Methyl-5-norbornene-2,3-dicarboxylic anhydride has been used:
  • as curing agent in the preparation of vertically aligned and penetrated carbon nanotube/polymer film
  • in the synthesis of methyl nadimides endcapped resins based on tris(3-aminophenyl)phosphine oxide

Signal Word

Danger

Hazard Statements

H302,H314,H317,H334

Hazard Classifications

Acute Tox. 4 Oral - Resp. Sens. 1 - Skin Corr. 1C - Skin Sens. 1

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

275.0 °F

Flash Point(C)

135 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

235431-1KG:
235431-VAR:
235431-BULK:
235431-250G:
235431-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV0133
MKCS1457
MKCS6656
MKCM9944
MKCL2321

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Methyl nadimide resins: Synthesis and characterization.
Alam S, et al.
Journal of Applied Polymer Science, 53(8), 1073-1081 (1994)
Aurelio Bifulco et al.
Polymers, 12(8) (2020-07-30)
Thermosetting polymers have been widely used in many industrial applications as adhesives, coatings and laminated materials, among others. Recently, bisphenol A (BPA) has been banned as raw material for polymeric products, due to its harmful impact on human health. On
Vertically aligned and penetrated carbon nanotube/polymer composite film and promising electronic applications.
Li Li et al.
Advanced materials (Deerfield Beach, Fla.), 23(32), 3730-3735 (2011-07-19)
Martina Sladkova et al.
Journal of tissue engineering and regenerative medicine, 12(3), 715-726 (2017-06-22)
Bone engineering opens the possibility to grow large amounts of tissue products by combining patient-specific cells with compliant biomaterials. Decellularized tissue matrices represent suitable biomaterials, but availability, long processing time, excessive cost, and concerns on pathogen transmission have led to
Chen Yu Huang et al.
Journal of molecular and cellular cardiology, 138, 1-11 (2019-10-28)
Recent advances in the understanding and use of pluripotent stem cells have produced major changes in approaches to the diagnosis and treatment of human disease. An obstacle to the use of human induced pluripotent stem cell-derived cardiomyocytes (hiPSC-CMs) for regenerative

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