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288055

Sigma-Aldrich

Cyclopentadienylmanganese(I) tricarbonyl

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About This Item

Linear Formula:
C5H5Mn(CO)3
CAS Number:
12079-65-1
Molecular Weight:
204.06
EC Number:
235-142-4
MDL number:
MFCD00001440
UNSPSC Code:
12352103
PubChem Substance ID:
24857312
NACRES:
NA.23

Quality Level

100

form

powder or crystals

composition

Mn, 26.0-27.9% EDTA titration

reaction suitability

core: manganese
reagent type: catalyst

mp

72-76 °C (lit.)

SMILES string

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1

InChI

1S/C5H5.3CO.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;;

InChI key

CZPHEHHRMHXAIK-UHFFFAOYSA-N

Related Categories

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H300

Precautionary Statements

P264 - P301 + P310

Hazard Classifications

Acute Tox. 2 Oral

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

288055-1G:4548173935720
288055-5G:
288055-VAR:
288055-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCF2541
MKCD8175
MKBZ0743V
MKBZ0742V
MKBX8112V

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K T Blanchard et al.
Toxicology letters, 70(2), 253-259 (1994-02-01)
The effect of m-xylene on the rat nasal cytochrome P450 (P450) mixed function oxidase system was analyzed in vitro utilizing microsomes isolated 2, 12, and 24 h following intraperitoneal administration of this solvent in vivo. For comparative purposes, pulmonary and
R J Clay et al.
Toxicology and applied pharmacology, 98(3), 434-443 (1989-05-01)
The acute pneumotoxic effects of cyclopentadienyl manganese tricarbonyl (CMT) and methylcyclopentadienyl manganese tricarbonyl (MMT) were compared to delineate the role of the methyl side chain in the toxicity of these organomanganese compounds and to further our understanding of the mechanisms
I Rémy et al.
Journal of pharmaceutical and biomedical analysis, 9(10-12), 965-967 (1991-01-01)
Biotin labelled with a cymantrene moiety (cyclopentadienyl manganese tricarbonyl complex) is described for the first time. Because this metallo-biotin retains full recognition for the specific glycoprotein avidin (or streptavidin), the labelled streptavidin-biotin system is proposed for use in a solid-phase
Magdaléna Hromadová et al.
Langmuir : the ACS journal of surfaces and colloids, 22(1), 506-511 (2005-12-28)
A first example of the solid-phase immunoassay of a high-weight antigen bovine serum albumin (BSA) using an (eta(5)-cyclopentadienyl)tricarbonylmanganese (cymantrene) redox probe is presented. The electrochemical detection is based on the impedance measurements of a one-electron reversible reduction of the organometallic
Katrin Splith et al.
Dalton transactions (Cambridge, England : 2003), 39(10), 2536-2545 (2010-02-25)
By combining organometallic groups and peptides, a large number of conjugates with interesting new biological properties can be prepared. Especially, attachment to cell-penetrating peptides (CPP) that act as efficient cell delivery vehicles has come to the fore. However, the presence
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