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309346

Sigma-Aldrich

L-Glutamic acid diethyl ester hydrochloride

97%

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About This Item

Linear Formula:
C2H5OCOCH2CH2CH(NH2)COOC2H5 · HCl
CAS Number:
1118-89-4
Molecular Weight:
239.70
Beilstein:
3597595
EC Number:
214-270-4
MDL number:
MFCD00012509
UNSPSC Code:
12352209
PubChem Substance ID:
24858729
NACRES:
NA.22

Quality Level

200

Assay

97%

optical activity

[α]18/D +22°, c = 1 in H2O

reaction suitability

reaction type: solution phase peptide synthesis

mp

108-110 °C (lit.)

application(s)

peptide synthesis

SMILES string

Cl[H].CCOC(=O)CC[C@H](N)C(=O)OCC

InChI

1S/C9H17NO4.ClH/c1-3-13-8(11)6-5-7(10)9(12)14-4-2;/h7H,3-6,10H2,1-2H3;1H/t7-;/m0./s1

InChI key

WSEQLMQNPBNMSL-FJXQXJEOSA-N

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Application

L-Glutamic acid diethyl ester hydrochloride can be used in the synthesis of:
  • Oligo(γ-ethyl L-glutamate) via oligomerization catalyzed by papain.
  • L-glutamic acid based dendritic compounds.
  • Poly(α-peptide) by polymerization and copolymerization in the presence of protease catalysts.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

309346-BULK:
309346-25G:
309346-5G:
309346-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
0000242152
0000128919
MKCK5271
MKAA3937V
BCBJ4838V

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Ultrasound induced formation of organogel from a glutamic dendron
Li Y, et al.
Tetrahedron, 63(31), 7468-7473 (2007)
M G Matheus et al.
Psychopharmacology, 132(1), 14-18 (1997-07-01)
Microinjections of glutamate into the dorsal periaqueductal grey (DPAG) of rats induce flight behavior, and blockade of glutamate NMDA receptors in the same region increases exploratory behavior of rats tested on the elevated plus maze. To investigate a possible role
Rapid regioselective oligomerization of L-glutamic acid diethyl ester catalyzed by papain
Li G, et al.
Macromolecules, 39(23), 7915-7921 (2006)
J Folbergrová
Experimental neurology, 130(2), 344-350 (1994-12-01)
Homocysteine induces seizures in adult, as well as in immature, experimental animals, but the mechanism of its action is still unknown. The aim of the present study was to examine whether homocysteine in immature animals may act via excitatory amino
W C Wu et al.
Journal of the autonomic nervous system, 67(3), 145-155 (1998-02-28)
The present study is designed to determine and characterize two neurobiological events. Firstly, we investigated whether increases of systemic arterial pressure (SAP) and sympathetic vertebral nerve activity (VNA) produced by microinjection of glycine (Gly) in the dorsomedial (DM) or rostral
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