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Safety Information

328219

Sigma-Aldrich

[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)

Synonym(s):

1,2-Ethylenebis(diphenylphosphine)nickel dichloride, Nickel 1,2-Bis(diphenylphosphino)ethane dichloride, [1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride, dppeNiCl2

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About This Item

Linear Formula:
[(C6H5)2PCH2CH2P(C6H5)2]NiCl2
CAS Number:
14647-23-5
Molecular Weight:
528.02
MDL number:
MFCD00013313
UNSPSC Code:
12161600
PubChem Substance ID:
24859721
NACRES:
NA.22

form

solid

Quality Level

100

reaction suitability

core: nickel
reagent type: catalyst

mp

263-265 °C (lit.)

SMILES string

Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4

InChI

1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChI key

XXECWTBMGGXMKP-UHFFFAOYSA-L

Related Categories

Application

Reactant involved in:
  • Kumada catalyst-transfer polycondensation
  • Oxidation of carboranyl phosphine ligands
  • Synthesis of nickel-iron dithiolato hydrides
  • Ullmann reactions - homocoupling reactions

Co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers

Catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes

related product

Product No.
Description
Pricing

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Specified Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

328219-1G:4548173294131
328219-5G:4548173294155
328219-25G:4548173294148
328219-BULK:
328219-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBP7538
SHBH8947
SHBC3753V
84896EJV
84896EJ

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Articles

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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