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Safety Information

361763

Sigma-Aldrich

2,3:5,6-Di-O-isopropylidene-α-D-mannofuranose

97%

Synonym(s):

D-Mannose diacetonide

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About This Item

Empirical Formula (Hill Notation):
C12H20O6
CAS Number:
14131-84-1
Molecular Weight:
260.28
Beilstein:
84382
MDL number:
MFCD00134206
UNSPSC Code:
12352201
PubChem Substance ID:
24862256
NACRES:
NA.22

Quality Level

100

Assay

97%

form

solid

optical activity

[α]20/D +23°, c = 1 in acetone

mp

125-126 °C (dec.) (lit.)

SMILES string

CC1(C)OC[C@@H](O1)[C@H]2OC(O)[C@@H]3OC(C)(C)O[C@@H]23

InChI

1S/C12H20O6/c1-11(2)14-5-6(16-11)7-8-9(10(13)15-7)18-12(3,4)17-8/h6-10,13H,5H2,1-4H3/t6?,7-,8+,9?,10?/m1/s1

InChI key

JWWCLCNPTZHVLF-RGJLLFKYSA-N

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Related Categories

Application

Protected mannose intermediate used in the syntheses of ovalicin and of the sugar core of hikizimycin.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

361763-BULK:
361763-1G:
361763-VAR:
361763-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS3522
MKCF0611
MKBW5300V
MKBP4367V
MKBN3366V

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Shunya Takahashi et al.
The Journal of organic chemistry, 70(24), 10162-10165 (2005-11-19)
[reaction: see text] A new synthesis of epoxyketone 22 is described that is a key intermediate in Barton's synthesis of ovalicin (2), a powerful anti-angiogenetic inhibitor. The key process for the construction of 22 was ring-closing metathesis of olefins 11
Furstner, A. et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 12, 76-76 (2006)

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