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Safety Information

410209

Sigma-Aldrich

L-Cysteine methyl ester hydrochloride

98%, for peptide synthesis

Synonym(s):

(R)-Cysteine methyl ester hydrochloride

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About This Item

Linear Formula:
HSCH2CH(NH2)COOCH3 · HCl
CAS Number:
18598-63-5
Molecular Weight:
171.65
Beilstein:
3685824
EC Number:
242-435-0
MDL number:
MFCD00038985
UNSPSC Code:
12352209
eCl@ss:
32160406
PubChem Substance ID:
24865699
NACRES:
NA.22

Product Name

L-Cysteine methyl ester hydrochloride, 98%

Quality Level

100

Assay

98%

form

solid

optical activity

[α]20/D −1.8°, c = 10 in methanol

reaction suitability

reaction type: solution phase peptide synthesis

mp

142 °C (dec.) (lit.)

application(s)

peptide synthesis

SMILES string

Cl[H].COC(=O)[C@@H](N)CS

InChI

1S/C4H9NO2S.ClH/c1-7-4(6)3(5)2-8;/h3,8H,2,5H2,1H3;1H/t3-;/m0./s1

InChI key

WHOHXJZQBJXAKL-DFWYDOINSA-N

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Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

410209-25G:
410209-5G:
410209-VAR:
410209-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
MKBX6175V
MKBS8811V
MKBP7996V
MKBH4741V
MKBF8304V

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Mohamed R Shehata et al.
Dalton transactions (Cambridge, England : 2003), (6)(6), 779-786 (2008-02-02)
The complex-formation equilibria of [Pd(SMC)(H2O)2]+, where SMC = S-methyl-l-cysteinate, with bio-relevant ligands such as amino acids, peptides, dicarboxylic acids and DNA constituents were studied and their formation constants were determined. The binding mode of the ligands containing various functional groups
A F Lailey et al.
Biochemical pharmacology, 42 Suppl, S47-S54 (1991-12-11)
Perfluoroisobutene (PFIB) is a hydrophobic reactive gas produced by the pyrolysis of polytetrafluoroethane which induces pulmonary oedema similar to that induced by phosgene when inhaled. When a lethal dose is inhaled by Porton strain rats total non-protein thiol (NPSH) and
Sandra Osburn et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(3), 873-879 (2011-01-13)
The structure and reactivity of the cysteine methyl ester radical cation, CysOMe(.+) , have been examined in the gas phase using a combination of experiment and density functional theory (DFT) calculations. CysOMe(.+) undergoes rapid ion-molecule reactions with dimethyl disulfide, allyl
Mickael Alimi et al.
Inorganic chemistry, 51(17), 9350-9356 (2012-08-22)
Six Co(III) complexes based on unsubstituted or substituted TPA ligands (where TPA is tris(2-pyridylmethyl)amine) and acetohydroxamic acid (A), N-methyl-acetohydroxamic acid (B), or N-hydroxy-pyridinone (C) were prepared and characterized by mass spectrometry, elemental analysis, and electrochemistry: [Co(III)(TPA)(A-2H)](Cl) (1a), [Co(III)((4-Cl(2))TPA)(A-2H)](Cl) (2a), [Co(III)((6-Piva)TPA)(A-2H)](Cl)
Itai Chipinda et al.
Chemical research in toxicology, 19(3), 341-350 (2006-03-21)
Diisocyanates (dNCOs) are the most commonly reported cause of chemically induced occupational asthma, but the ultimate antigenic form is unknown. Reactions of the three most common monomeric dNCOs, hexamethylene dNCO (HDI), methylene diphenylisocyanate (MDI), and toluene dNCO (TDI), with cysteine
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