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424684

Sigma-Aldrich

Phenethylmagnesium chloride solution

1.0 M in THF

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About This Item

Linear Formula:
C6H5CH2CH2MgCl
CAS Number:
90878-19-6
Molecular Weight:
164.92
MDL number:
MFCD00192387
UNSPSC Code:
12352103
PubChem Substance ID:
24866584
NACRES:
NA.22

Quality Level

200

reaction suitability

reaction type: Grignard Reaction

concentration

1.0 M in THF

bp

65 °C

density

0.954 g/mL at 25 °C

functional group

phenyl

SMILES string

Cl[Mg]CCc1ccccc1

InChI

1S/C8H9.ClH.Mg/c1-2-8-6-4-3-5-7-8;;/h3-7H,1-2H2;1H;/q;;+1/p-1

InChI key

AZORNQXQALOFHH-UHFFFAOYSA-M

Related Categories

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH014,EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

1.4 °F - closed cup

Flash Point(C)

-17 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Organometallic compounds
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

424684-BULK:
424684-800ML:4548173148717
424684-100ML:4548173148700
424684-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBQ9255
SHBP8337
SHBP4231
SHBL8586
SHBL6675

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Oleg V Larionov et al.
Organic letters, 16(3), 864-867 (2014-01-15)
A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of copper catalysis and activation by lithium fluoride or magnesium chloride. The utility of this method

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