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442585

Sigma-Aldrich

Pentafluorophenylmagnesium bromide solution

0.5 M in diethyl ether

Synonym(s):

(Perfluorophenyl)magnesium bromide, 2,3,4,5,6-Pentafluorophenylmagnesium bromide, Bromo(pentafluorophenyl)magnesium

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About This Item

Linear Formula:
C6F5MgBr
CAS Number:
879-05-0
Molecular Weight:
271.27
Beilstein:
3611565
MDL number:
MFCD00015720
UNSPSC Code:
12352103
PubChem Substance ID:
24867918
NACRES:
NA.22

form

liquid

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

concentration

0.5 M in diethyl ether

bp

34.6 °C

density

0.861 g/mL at 25 °C

functional group

fluoro

SMILES string

Fc1c(F)c(F)c([Mg]Br)c(F)c1F

InChI

1S/C6F5.BrH.Mg/c7-2-1-3(8)5(10)6(11)4(2)9;;/h;1H;/q;;+1/p-1

InChI key

AXQVMJIDNDRSFM-UHFFFAOYSA-M

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Application

Employed in the synthesis of novel arsonic and arsinic acids as ligands for potential transition-metal ion extractants, and in the synthesis of polyfluoroaryl alkyl sulfides.

Signal Word

Danger

Hazard Statements

H224,H302,H314,H336

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system

Supplementary Hazards

EUH014,EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-40.0 °F - closed cup

Flash Point(C)

-40 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Organometallic compounds
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

442585-BULK-A:
442585-100ML-A:4548173151595
442585-VAR-A:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBQ1665
SHBN5071
SHBK5316
SHBH5449V
SHBF9297V

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Journal of Fluorine Chemistry, 73, 73-73 (1995)
Solvent Extr. Ion Exch., 14, 417-417 (1996)

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