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464872

Sigma-Aldrich

Lithium diphenylphosphide solution

0.5 M in THF

Synonym(s):

Diphenyl lithium phosphide, Diphenylphosphine lithium salt, Diphenylphosphino)lithium, Lithiodiphenyl phosphide, Lithiodiphenylphosphine

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About This Item

Linear Formula:
(C6H5)2PLi
CAS Number:
65567-06-8
Molecular Weight:
192.12
MDL number:
MFCD00046054
UNSPSC Code:
12352002
PubChem Substance ID:
24870228
NACRES:
NA.22

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Quality Level

100

concentration

0.5 M in THF

bp

65-67 °C

density

0.925 g/mL at 25 °C

SMILES string

[Li]P(c1ccccc1)c2ccccc2

InChI

1S/C12H10P.Li/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;/q-1;+1

InChI key

WKUYEGHEUWHKIU-UHFFFAOYSA-N

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

-4.0 °F - closed cup

Flash Point(C)

-20 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Organometallic compounds
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

464872-100ML:4548173155203
464872-1L:4548173155210
464872-VAR:
464872-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBQ3467
SHBM4366
SHBG4606V
SHBD2668V
SHBB4577V

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