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Safety Information

499382

Sigma-Aldrich

2-Pyridylzinc bromide solution

0.5 M in THF

Synonym(s):

Bromo-2-pyridinylzinc, Pyridin-2-ylzinc bromide

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About This Item

Empirical Formula (Hill Notation):
C5H4BrNZn
CAS Number:
218777-23-2
Molecular Weight:
223.39
MDL number:
MFCD00671985
UNSPSC Code:
12352103
PubChem Substance ID:
24873276
NACRES:
NA.22

Quality Level

100

concentration

0.5 M in THF

density

0.974 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Br[Zn]c1ccccn1

InChI

1S/C5H4N.BrH.Zn/c1-2-4-6-5-3-1;;/h1-4H;1H;/q;;+1/p-1

InChI key

XYTLXTHDABUPLT-UHFFFAOYSA-M

Related Categories

Application

Used in the preparation of P,N ligands for asymmetric Ir-catalyzed reactions.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2

Target Organs

Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

1.0 °F - closed cup

Flash Point(C)

-17.2 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Materials containing Organometallic compounds
Hazardous rank II
2nd spontaneously combustible materials and water reactive materials

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

499382-VAR:
499382-50ML:4548173163888
499382-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBS0553
SHBQ8321
SHBN5800
BCCF9700
SHBM5001

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New P,N ligands for asymmetric Ir-catalyzed reactions.
Tanasri Bunlaksananusorn et al.
Angewandte Chemie (International ed. in English), 42(33), 3941-3943 (2003-09-02)

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