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525855

Sigma-Aldrich

Diethyl allyl phosphate

98%

Synonym(s):

Allyl ethyl phosphate, Diethyl 2-propen-1-yl phosphate

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About This Item

Linear Formula:
H2C=CHCH2OP(O)(OC2H5)2
CAS Number:
3066-75-9
Molecular Weight:
194.17
MDL number:
MFCD02683550
UNSPSC Code:
12352100
PubChem Substance ID:
24874513
NACRES:
NA.22

Quality Level

100

Assay

98%

refractive index

n20/D 1.422 (lit.)

bp

45-46 °C (lit.)

density

1.09 g/mL at 25 °C (lit.)

functional group

phosphate

SMILES string

CCOP(=O)(OCC)OCC=C

InChI

1S/C7H15O4P/c1-4-7-11-12(8,9-5-2)10-6-3/h4H,1,5-7H2,2-3H3

InChI key

GZNJJEODYYLYSA-UHFFFAOYSA-N

General description

Diethyl allyl phosphate can be prepared by reacting ethanol and POCl3.It can undergo free radical polymerization to form a flame retardant polymer, poly DEAP

Application

DEAP may be used as a flame retardant additive in the preparation of rubber wood/polymer composite. It can also be used for the stereoselective synthesis of cis- or trans-3-vinyl-β-lactam compounds and also for the fabrication of amphoteric surfaces on silicone substrates.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

525855-VAR:
525855-25G:
525855-BULK:
525855-5G:

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Certificates of Analysis (COA)

Lot/Batch Number
0000338359
0000314099
0000218009
0000238442
0000203711

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dimethyl phosphate AldrichCPR

Sigma-Aldrich

CDS014665

dimethyl phosphate

A new polymeric flame retardant additive for vinyl polymers.
Sundarrajan S, et al.
Indian J. Chem. A, 40(1), 41-45 (2001)
Carbonylative [2+ 2] cycloaddition for the construction of ?-lactam skeleton with palladium catalyst.
Torii S, et al.
Tetrahedron Letters, 34(41), 6553-6556 (1993)
Modification of rubber wood with styrene in combination with diethyl allyl phosphate as the flame-retardant agent.
Devi RR, et al.
Journal of Applied Polymer Science, 105(5), 2461-2467 (2007)
Ebru Akdoğan et al.
Colloids and surfaces. B, Biointerfaces, 89, 289-294 (2011-10-04)
Amphoteric surfaces were generated on silicone substrates via plasma polymerization technique using a single monomer; diethyl allyl phosphate (DAP). Surface characterization was performed by the means of contact angle titration and Fourier transform infrared (FTIR) spectroscopy. The surface of silicone

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