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647640

Sigma-Aldrich

Zirconium(IV) chloride

anhydrous, powder, 99.99% trace metals basis

Synonym(s):

Tetrachlorozirconium, Zirconium tetrachloride

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About This Item

Linear Formula:
ZrCl4
CAS Number:
10026-11-6
Molecular Weight:
233.04
EC Number:
233-058-2
MDL number:
MFCD00011306
UNSPSC Code:
12352302
PubChem Substance ID:
24883414
NACRES:
NA.23

grade

anhydrous

Quality Level

100

vapor pressure

1 mmHg ( 190 °C)

Assay

99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: zirconium

impurities

<50 ppm hafnium

transition temp

sublimation point 331 °C

density

2.8 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

Cl[Zr](Cl)(Cl)Cl

InChI

1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4

InChI key

DUNKXUFBGCUVQW-UHFFFAOYSA-J

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General description

Zirconium(IV) chloride (ZrCl4) is a Lewis acid catalyst, which has low toxicity. It is a moisture resistant material that is used as a catalyst in organic transformations.

Application

ZrCl4 can be used as a catalyst for a variety of organic syntheses, such as Friedel-Crafts reaction, condensation reaction and other reduction reactions.

accessory

Product No.
Description
Pricing

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H290,H314

Hazard Classifications

Met. Corr. 1 - Skin Corr. 1B

Supplementary Hazards

EUH014,EUH071

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

647640-25G:4548173945217
647640-VAR:
647640-BULK:
647640-5G-PW:
647640-25G-PW:
647640-5G:4548173945224

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Certificates of Analysis (COA)

Lot/Batch Number
0000406810
0000282375
0000406810
0000292361
0000292362

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Synthesis of 2, 3-dihydroquinazolin-4 (1H)-ones catalyzed by zirconium (IV) chloride as a mild and efficient catalyst
Abdollahi-Alibeik M and Shabani E
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 22(10), 1163-1166 (2011)
Erik A Wu et al.
Nature communications, 12(1), 1256-1256 (2021-02-25)
Rechargeable solid-state sodium-ion batteries (SSSBs) hold great promise for safer and more energy-dense energy storage. However, the poor electrochemical stability between current sulfide-based solid electrolytes and high-voltage oxide cathodes has limited their long-term cycling performance and practicality. Here, we report
Applications of zirconium (IV) chloride in organic synthesis
Smitha G, et al.
Synthesis, 2008(06), 829-855 (2008)
Xiaoyin Xiao et al.
Langmuir : the ACS journal of surfaces and colloids, 27(15), 9484-9489 (2011-06-28)
We used positively charged lipids to prepare lipid bilayer assemblies (LBAs) upon which we assembled negatively charged gold nanoparticles (AuNPs). Treatment of the assembly with zirconium chloride resulted in the formation of nanorings of the diameters inversely related to the
A Z El-Sonbati et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(7), 1411-1424 (2002-06-27)
Some binary and ternary novel complexes of dioxouranium(VI) with 5-vinylsalicylaldehyde (VSH) have been prepared and characterized by various physico-chemical techniques. The amine exchange reactions of coordinated poly-Schiff bases in these complexes have been also carried out which give symmetrical tetradentate
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