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674583

Sigma-Aldrich

Silver perchlorate

anhydrous, 97%

Synonym(s):

Perchloric acid silver(1+) salt, Silver(1+) perchlorate

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About This Item

Linear Formula:
AgClO4
CAS Number:
7783-93-9
Molecular Weight:
207.32
EC Number:
232-035-4
MDL number:
MFCD00003400
UNSPSC Code:
12352302
PubChem Substance ID:
24885223
NACRES:
NA.23
Assay:
97%
grade:
anhydrous
form:
solid
solubility:
benzene: slightly soluble(lit.)
pyridine: slightly soluble(lit.)

grade

anhydrous

Quality Level

100

Assay

97%

form

solid

reaction suitability

reagent type: catalyst
core: silver

impurities

≤0.1% Insoluble matter

mp

486 °C (lit.)

solubility

benzene: slightly soluble(lit.)
pyridine: slightly soluble(lit.)

density

2.8 g/mL at 25 °C (lit.)

SMILES string

[Ag+].[O-]Cl(=O)(=O)=O

InChI

1S/Ag.ClHO4/c;2-1(3,4)5/h;(H,2,3,4,5)/q+1;/p-1

InChI key

YDHABVNRCBNRNZ-UHFFFAOYSA-M

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Application

  • Anion exchange dynamics in the capture of perchlorate by a cationic Ag-based MOF: Investigates the anion exchange dynamics and structural transformations of a silver-based metal-organic framework capturing perchlorate (Colinas et al., 2017).

Pictograms

Flame over circleCorrosion
GHS03,GHS05

Signal Word

Danger

Hazard Statements

H272,H314

Hazard Classifications

Ox. Sol. 2 - Skin Corr. 1B

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class I Designated Chemical Substances

FSL

Group 1: Oxidizing solids
Perchlorates
Hazardous rank I
1st oxidizing solid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

674583-BULK:
674583-VAR:
674583-25G:4548173227368
674583-5G:4548173227375

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW2275
MKCV6734
MKCT6666
MKCS7083
MKCQ4873

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C Rentel et al.
Analytical chemistry, 70(20), 4394-4400 (1998-10-31)
In LC/MS, nonpolar substances in the majority of cases cannot be ionized by standard electrospray ionization (ESI) because they obviously lack a site for protonation or deprotonation. The ionization of carotenoids and tocopherols can be greatly enhanced by the addition
E Petráková et al.
Carbohydrate research, 233, 101-112 (1992-09-02)
Specifically deoxygenated methyl alpha-isomaltotriosides were synthesized by the silver perchlorate-mediated condensation of a protected alpha-isomaltosyl chloride with suitably blocked derivatives of methyl alpha-D-glucopyranoside deoxygenated respectively at positions 2, 3, and 4, followed by deprotection.
Masafumi Harada et al.
Journal of colloid and interface science, 339(2), 373-381 (2009-09-08)
Metal particles of silver (Ag) were synthesized by the photoreduction of silver perchlorate (AgClO(4)) in water-in-ionic liquid (ILs) microemulsions consisting of Tween 20, water and ionic liquids. The ILs were tetrafluoroborate anions associated with the cations 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF(4)]) and
Ken Sakai et al.
Acta crystallographica. Section B, Structural science, 60(Pt 3), 255-262 (2004-05-19)
The third crystal structure containing the hydroxo-bridged cis-diammineplatinum(II) dimer has been determined for a perchlorate salt of the complex, [Pt(2)(NH(3))(4)(micro-OH)(2)](ClO(4))(2). However, the dinuclear cations in the nitrate and the carbonate salts, [Pt(2)(NH(3))(4)(micro-OH)(2)](NO(3))(2) [Faggiani, Lippert, Lock & Rosenberg (1977). J. Am.
Glycosylation via Cp2ZrCl2/AgClO4-mediated activation of anomeric sulfoxides.
P Wipf et al.
The Journal of organic chemistry, 66(23), 7910-7914 (2001-11-10)
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