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Safety Information

700665

Sigma-Aldrich

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

Synonym(s):

(R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate

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About This Item

Empirical Formula (Hill Notation):
C48H29O4P
CAS Number:
864943-22-6
Molecular Weight:
700.72
MDL number:
MFCD12546016
UNSPSC Code:
12352005
PubChem Substance ID:
329762222
NACRES:
NA.22

form

solid

Quality Level

100

optical activity

[α]22/D −44.0°, c = 1 in DMSO

mp

390-400 °C

functional group

phosphate

storage temp.

−20°C

SMILES string

OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)-c6cc7ccccc7c8ccccc68)-c9cc%10ccccc%10c%11ccccc9%11

InChI

1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50)

InChI key

BVICVEIKBNVROI-UHFFFAOYSA-N

Application

Catalyst for:
  • Asymmetric hydrogenation cascade
  • Enantioselective Friedel-Crafts reaction
  • Asymmetric hydrogenation of 2-substituted quinolines
  • Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
  • Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
  • Asymmetric transfer hydrogenation of substituted quinoxalines

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

700665-100MG:
700665-BULK:
700665-VAR:
700665-500MG:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCJ6782
MKBX5718V
MKBT4459V
07202HJ

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