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713031

Sigma-Aldrich

1-Ethyl-3-methylimidazolium iodide

97%

Synonym(s):

EMIMI

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About This Item

Empirical Formula (Hill Notation):
C6H11IN2
CAS Number:
Molecular Weight:
238.07
Beilstein:
5160333
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
form:
powder
Assay:
≥96.5% (HPLC)
97%

Quality Level

Assay

≥96.5% (HPLC)
97%

form

powder

impurities

≤0.5% water

SMILES string

[I-].CCn1cc[n+](C)c1

InChI

1S/C6H11N2.HI/c1-3-8-5-4-7(2)6-8;/h4-6H,3H2,1-2H3;1H/q+1;/p-1

InChI key

IKQCDTXBZKMPBB-UHFFFAOYSA-M

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General description

1-Ethyl-3-methylimidazolium iodide is an ionic liquid that can be prepared by reacting methylimidazole with iodoethane. The addition of EMImI to 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF4), increase its capacitance while developing electric double-layer capacitors (EDLCs) based on EMImBF4.

Application

EMImI reacts with aluminum chloride to form 1-ethyl-3-methylimidazolium halogenoaluminate ionic liquid, [emim]I–(AlCl3)x, which is an excellent solvent for Friedel–Crafts acylation of ferrocene.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

713031-5G:4548173998688
713031-BULK:
713031-50G:4548173998671
713031-VAR:


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1-Ethyl-3-methylimidazolium halogenoaluminate ionic liquids as solvents for Friedel-Crafts acylation reactions of ferrocene.
MacLean B and Singer R.
J. Chem. Soc., Dalton Trans., 1, 63-66 (1999)
Mass and Charge Transport in the Polymer?Ionic-Liquid System PEO?EMImI: From Ionic-Liquid-in-Polymer to Polymer-in-Ionic-Liquid Electrolytes
Ko?sters, Johannes, Monika Scho?nhoff, and Nicolaas A. Stolwijk
The Journal of Physical Chemistry B, 119.17, 5693-5700 (2015)
Electrochemical study of copper in a basic 1-ethyl-3-methylimidazolium tetrafluoroborate room temperature molten salt
Chen, Po-Yu, and I-Wen Sun
Electrochimica Acta, 45.3, 441-450 (1999)
Electrochemical characteristics pyrolytic graphite| mixture of 1-ethyl-3-methylimidazolium tetrafluoroborate and 1-ethyl-3-methylimidazolium iodide interface
Siinor, Liis, et al.
Journal of Electroanalytical Chemistry, 719, 133-137 (2014)
The electrochemical characteristics of the mixture of 1-ethyl-3-methylimidazolium tetrafluoroborate and 1-ethyl-3-methylimidazolium iodide
Siimenson, Carolin, et al.
Journal of Electroanalytical Chemistry, 730, 59-64 (2014)

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