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766127

Sigma-Aldrich

2,5-Dilfuoro-4-methoxyphenylzinc bromide solution

0.6 M in THF

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About This Item

Empirical Formula (Hill Notation):
C7H5BrF2OZn
Molecular Weight:
288.40
MDL number:
MFCD13152552
UNSPSC Code:
12352103
PubChem Substance ID:
329767210
NACRES:
NA.22

form

liquid

Quality Level

100

reaction suitability

core: zinc
reagent type: catalyst
reaction type: Negishi Coupling
reagent type: derivatization reagent
reaction type: Negishi Coupling

concentration

0.6 M in THF

density

1.029 g/mL at 25 °C

functional group

fluoro

storage temp.

2-8°C

SMILES string

COc1cc(F)c([Zn]Br)cc1F

InChI

1S/C7H5F2O.BrH.Zn/c1-10-7-4-5(8)2-3-6(7)9;;/h3-4H,1H3;1H;/q;;+1/p-1

InChI key

WEUAQJYCDOJDPB-UHFFFAOYSA-M

Related Categories

Application

Nucleophlic reagent applicable for substitution and addition reactions. Also could be used in cross coupling reactions (Negishi couplings).

Organozinc Reagents

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-4.0 °F

Flash Point(C)

-20 °C

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 4: Flammable liquids
Type 1 petroleums
Hazardous rank II
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

766127-BULK:
766127-50ML:
766127-25ML:
766127-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
MKBL7260V

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