794473

Ritter Trifluoroiodomethane-TMG Reagent

• Synonym(s): TMG-CF₃I, Tetramethylguanidine-trifluoromethyl iodide adduct
• Empirical Formula (Hill Notation): C₆H₁₃F₃IN₃
• Molecular Weight: 311.09
• MDL number: MFCD28899637
• UNSPSC Code: 12352101
• PubChem Substance ID: 329768452

Properties

• form: liquid
• Quality Level: 100
• reaction suitability: reaction type: C-C Bond Formation
• refractive index: n/D 1.461
• density: 1.495 g/mL at 25 °C
• functional group: amine; fluoro; iodo
• shipped in: dry ice
• storage temp.: 2-8°C
• SMILES string: FC(F)(F)I.N=C(N(C)C)N(C)C
• InChI: 1S/C5H13N3.CF3I/c1-7(2)5(6)8(3)4;2-1(3,4)5/h6H,1-4H3;
• InChI key: KIOFDNCUJQQUCD-UHFFFAOYSA-N

Description

Application

Product is a more convenient, liquified version of trifluoroiodomethane, which can be utilized in photocatalytic and electrophilic pentafluoroethylation of olefins and heteroatoms respectively.

Other Notes

Condensed-Phase, Halogen-Bonded CF₃I and C₂F₅I Adducts for Perfluoroalkylation Reactions

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): No data available
• Flash Point(C): No data available