809330

Fe/ppm Pd for nitro group reductions

• MDL number: MFCD00011005
• UNSPSC Code: 12161600
• NACRES: NA.22

Properties

• form: solid
• Quality Level: 100
• composition: FeCl₂ (372870), 23.3-27.4 wt. % ; MgCl₂ (M8266), 15.3-18.8 wt. % ; Pd (203939), <0.3 wt. % ; THF (186562), 53.5-61.6 wt. %
• reaction suitability: core: iron; reagent type: catalyst
• storage temp.: 2-8°C
• SMILES string: [Fe](Cl)(Cl)Cl

Description

Application

When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.

Caution

Handle under nitrogen and store under argon in refrigerator.

Other Notes

Safe and Selective Nitro Group Reductions Catalyzed by Sustainable and Recyclable Fe/ppm Pd Nanoparticles in Water at Room Temperature

Watch Professor Lipshutz talk about Fe/ppm Pd in this webinar:
From milligrams to kilograms: synthetic chemistry following nature′s lead

Safety Information

• Pictograms: GHS02,GHS08,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H290,H302,H318,H335,H351
• Precautionary Statements: P201 - P210 - P233 - P261 - P280 - P305 + P351 + P338 + P310
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH018,EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 2
• Flash Point(F): 1.4 °F
• Flash Point(C): -17 °C