87189

1-Tetradecene

≥97.0% (GC)

• Synonym(s): 1-Butadecene, n-Tetradec-1-ene, alpha-Tetradecene
• Linear Formula: CH₃(CH₂)₁₁CH=CH₂
• CAS Number: 1120-36-1
• Molecular Weight: 196.37
• Beilstein: 1701156
• EC Number: 214-306-9
• MDL number: MFCD00008981
• UNSPSC Code: 12352100
• PubChem Substance ID: 57653175
• NACRES: NA.22

Properties

• vapor density: 6.8 (vs air)
• Quality Level: 100
• Assay: ≥97.0% (GC)
• form: liquid
• autoignition temp.: 455 °F
• refractive index: n20/D 1.436 (lit.); n20/D 1.436
• bp: 251 °C (lit.)
• mp: −13-−11 °C (lit.)
• density: 0.775 g/mL at 25 °C (lit.)
• functional group: allyl
• SMILES string: CCCCCCCCCCCCC=C
• InChI: 1S/C14H28/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3H,1,4-14H2,2H3
• InChI key: HFDVRLIODXPAHB-UHFFFAOYSA-N

Description

Application

1-Tetradecene can be used as a reactant to synthesize:

• 2-Tetradecanone via PdCl₂/CrO₃ catalyzed oxidation reaction.
• (E)-ethyl pentadec-2-enoate, which is used as a key intermediate in the diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid via Johnson-Claisen rearrangement.

It can also be used as a monomer unit to synthesize high molecular weight polymer [poly(1- tetradecene)] by titanium complex catalyzed polymerization reaction.

Safety Information

• Pictograms: GHS08
• Signal Word: Danger
• Hazard Statements: H304
• Precautionary Statements: P301 + P310 - P331 - P405 - P501
• Hazard Classifications: Asp. Tox. 1
• Supplementary Hazards: EUH066
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 230.0 °F
• Flash Point(C): 110 °C
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves