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926736

Sigma-Aldrich

MNBO

≥95%

Synonym(s):

N-Benzyl-N-(2-methylnaphthalen-1-yl)oxalamide

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About This Item

Empirical Formula (Hill Notation):
C20H18N2O2
CAS Number:
2072108-68-8
Molecular Weight:
318.37
UNSPSC Code:
12352101
NACRES:
NA.21

Quality Level

100

Assay

≥95%

form

powder

mp

202-203 °C

storage temp.

−20°C

Application

MNBO is a ligand for the copper-catalyzed Ullman-Ma cross-coupling reaction.

Other Notes

Discovery of N-(Naphthalen-1-yl)-N′-alkyl Oxalamide Ligands Enables Cu-Catalyzed Aryl Amination with High Turnovers

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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

926736-250MG:
926736-VAR:
926736-1G:
926736-BULK:

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Jie Gao et al.
Organic letters, 19(11), 2809-2812 (2017-05-23)
A class of N-(naphthalen-1-yl)-N'-alkyl oxalamides have been proven to be powerful ligands, making a coupling reaction of (hetero)aryl iodides with primary amines proceed at 50 °C with only 0.01 mol % of Cu2O and ligand as well as a coupling

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