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Safety Information

N32601

Sigma-Aldrich

Norcamphor

98%

Synonym(s):

2-Norbornanone, Bicyclo[2.2.1]heptan-2-one

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About This Item

Empirical Formula (Hill Notation):
C7H10O
CAS Number:
497-38-1
Molecular Weight:
110.15
Beilstein:
1209657
EC Number:
207-846-1
MDL number:
MFCD00074823
UNSPSC Code:
12352100
PubChem Substance ID:
24897635
NACRES:
NA.22

Quality Level

100

Assay

98%

form

crystals

bp

168-172 °C (lit.)

mp

93-96 °C (lit.)

SMILES string

O=C1C[C@@H]2CC[C@H]1C2

InChI

1S/C7H10O/c8-7-4-5-1-2-6(7)3-5/h5-6H,1-4H2/t5-,6+/m1/s1

InChI key

KPMKEVXVVHNIEY-RITPCOANSA-N

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Related Categories

Pictograms

Flame
GHS02

Signal Word

Danger

Hazard Statements

H228

Precautionary Statements

P210

Hazard Classifications

Flam. Sol. 1

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

91.4 °F - closed cup

Flash Point(C)

33 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 2: Flammable solids
Flammable solid
Hazardous rank III

JAN Code

N32601-25G:
N32601-BULK:
N32601-100G:
N32601-5G:
N32601-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS8807
MKCS8806
MKCP9920
MKBL6578V
MKBK4414V

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Bicyclo[2.2.1]hept-2-ene 99%

Sigma-Aldrich

N32407

Bicyclo[2.2.1]hept-2-ene

M B Bass et al.
Proteins, 13(1), 26-37 (1992-05-01)
While cytochrome P-450cam catalyzes the hydroxylation of camphor to 5-exo-hydroxycamphor with 100% stereospecificity, norcamphor is hydroxylated by this enzyme yielding 45% 5-exo-, 47% 6-exo-, and 8% 3-exo-hydroxynorcamphor (Atkins, W.M., Sligar, S.G., J. Am. Chem. Soc. 109:3754-3760, 1987). The present study
P J Loida et al.
The Journal of biological chemistry, 270(10), 5326-5330 (1995-03-10)
The stereoselectivity of cytochrome P450cam hydroxylation has been investigated with the enantiomerically pure substrate analog norcamphor. (1R)- and (1S)-norcamphor (> 92 enantiomeric excess) were characterized in the hydroxylation reaction with cytochrome P450cam with respect to the product profile, steady state
Christiane Jung et al.
European journal of biochemistry, 269(12), 2989-2996 (2002-06-20)
The high-pressure stopped-flow technique is applied to study the CO binding in cytochrome P450cam (P450cam) bound with homologous substrates (1R-camphor, camphane, norcamphor and norbornane) and in the substrate-free protein. The activation volume DeltaV # of the CO on-rate is positive
Megan C Thielges et al.
The journal of physical chemistry. A, 115(34), 9714-9723 (2011-06-09)
Progress in the field of 2D IR vibrational spectroscopy has been bolstered by the production of intense mid-IR laser pulses. As higher-energy pulses are employed, a concomitant increase occurs in the likelihood of fifth-order contributions to the 2D IR spectra.
J Contzen et al.
Biochemistry, 37(13), 4317-4324 (1998-04-29)
Step-scan time-resolved Fourier transform infrared spectroscopy with a time resolution of 5 micros was applied to the carbon monoxide complex of cytochrome P-450cam (CYP101) to study the bimolecular ligand-rebinding process after flash photolysis. Spectral changes in the CO ligand stretch
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