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14023

Sigma-Aldrich

Titanium(IV) oxysulfate

≥29% Ti (as TiO2) basis, technical

Synonym(s):

Titanyl sulfate

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About This Item

Linear Formula:
TiOSO4 · aq
CAS Number:
13825-74-6
Molecular Weight:
159.93 (anhydrous basis)
MDL number:
MFCD00149873
UNSPSC Code:
12161600
PubChem Substance ID:
57647130
NACRES:
NA.22

Quality Level

200

grade

technical

form

solid

reaction suitability

core: titanium
reagent type: catalyst

concentration

≥29% (Ti (as TiO2))

impurities

sulfonic acid
≤17% free acid (as H2SO4)

anion traces

chloride (Cl-): ≤500 mg/kg

cation traces

Fe: ≤500 mg/kg

SMILES string

O.O=[Ti++].[O-]S([O-])(=O)=O

InChI

1S/H2O4S.H2O.O.Ti/c1-5(2,3)4;;;/h(H2,1,2,3,4);1H2;;/q;;;+2/p-2

InChI key

SWNAGNPMPHSIJF-UHFFFAOYSA-L

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Application

Titanium(IV) oxysulfate has been used as a precursor to synthesize a wide range of titanium dioxide (TiO2) photocatalysts.
It can also be used in the synthesis of freeze dried titania foams, and WO3-loaded TiO2 photocatalyst applicable for the oxidation of trans-ferulic acid to vanillin.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H290,H314

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

14023-1KG:4548173291239
14023-6X1KG:4548173291260
14023-BULK:
14023-50KG:4548173291246
14023-VAR:
14023-100G:4548173291222
14023-6X100G:4548173291253

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB0677
STBK5843
STBK3086
STBK1389
STBJ9070

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Photocatalytic oxidation of trans-ferulic acid to vanillin on TiO2 and WO3-loaded TiO2 catalysts
Di Paola A, et al.
Catalysis Today, 252, 195-200 (2015)
Highly photoactive 2D titanium dioxide nanostructures prepared from lyophilized aqueous colloids of peroxo-polytitanic acid
Subrt J, et al.
Materials Research Bulletin, 49, 405-412 (2014)
Karoly Kozma et al.
Dalton transactions (Cambridge, England : 2003), 48(29), 11086-11093 (2019-07-02)
TiO2 is manufactured for white pigments, solar cells, self-cleaning surfaces and devices, and other photocatalytic applications. The industrial synthesis of TiO2 entails: (1) the dissolution of ilmenite ore (FeTiO3) in aqueous sulfuric acid which precipitates the Fe while retaining the
Photocatalytic green synthesis of piperonal in aqueous TiO2 suspension
Bellardita M, et al.
Applied Catalysis. B, Environmental, 144, 607-613 (2014)
Stanislav S Fedotov et al.
Nature communications, 11(1), 1484-1484 (2020-03-22)
The rapid progress in mass-market applications of metal-ion batteries intensifies the development of economically feasible electrode materials based on earth-abundant elements. Here, we report on a record-breaking titanium-based positive electrode material, KTiPO4F, exhibiting a superior electrode potential of 3.6 V in
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