306975

tert-Butyl methyl ether

anhydrous, 99.8%

• Synonym(s): MTBE, Methyl tert-butyl ether
• Linear Formula: (CH₃)₃COCH₃
• CAS Number: 1634-04-4
• Molecular Weight: 88.15
• Beilstein: 1730942
• EC Number: 216-653-1
• MDL number: MFCD00008812
• UNSPSC Code: 12352112
• PubChem Substance ID: 57648465
• NACRES: NA.21
• grade: anhydrous
• Assay: 99.8%
• bp: 55-56 °C (lit.)
• vapor pressure: 4.05 psi

Properties

• grade: anhydrous
• Quality Level: 100
• vapor density: 3.1 (vs air)
• vapor pressure: 4.05 psi
• Assay: 99.8%
• form: liquid
• autoignition temp.: 705 °F
• expl. lim.: 15.1 %
• impurities: <0.003% water; <0.005% water (100 mL pkg)
• evapn. residue: <0.0005%
• refractive index: n20/D 1.369 (lit.)
• bp: 55-56 °C (lit.)
• mp: -110 °C
• density: 0.74 g/mL at 25 °C (lit.)
• SMILES string: COC(C)(C)C
• InChI: 1S/C5H12O/c1-5(2,3)6-4/h1-4H3
• InChI key: BZLVMXJERCGZMT-UHFFFAOYSA-N

Description

General description

tert-Butyl methyl ether (MTBE) is a gasoline additive. MTBE undergoes oxidative degradation in the presence of propane-oxidizing bacterial strains. The kinetic studies of heat-assisted persulfate oxidation of MTBE under various parameters suggests that the reaction follows the pseudo-first-order kinetics. MTBE can be synthesized by acid catalyzed reaction between methanol and isobutene. A study suggests that the addition of MTBE increases the number of active sites during polymerization of propene by stopped-flow method.

tert-Butyl methyl ether is a commonly used organic solvent that can be synthesized by acid catalyzed reaction between methanol and isobutene. It is an effective alternative to lead containing additives for enhancing the octane rating of gasoline.

Application

tert-Butyl methyl ether may be used to synthesize fatty acid methyl esters (FAMEs) and glycerol tert-butyl ether via transesterification with canola oil under supercritical conditions.

Safety Information

• Pictograms: GHS02,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H315
• Precautionary Statements: P210 - P233 - P240 - P241 - P242 - P303 + P361 + P353
• Hazard Classifications: Flam. Liq. 2 - Skin Irrit. 2
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 1
• Flash Point(F): -18.4 °F - closed cup
• Flash Point(C): -28 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves