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Safety Information

440108

Sigma-Aldrich

Trichloro(phenyl)silane

≥97.0%

Synonym(s):

Phenyltrichlorosilane

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About This Item

Linear Formula:
C6H5SiCl3
CAS Number:
98-13-5
Molecular Weight:
211.55
EC Number:
202-640-8
MDL number:
MFCD00000479
UNSPSC Code:
12352100
PubChem Substance ID:
57650206
NACRES:
NA.21

Quality Level

100

Assay

≥97.0%

form

liquid

refractive index

n20/D 1.523 (lit.)

bp

201 °C (lit.)

density

1.321 g/mL at 25 °C (lit.)

SMILES string

Cl[Si](Cl)(Cl)c1ccccc1

InChI

1S/C6H5Cl3Si/c7-10(8,9)6-4-2-1-3-5-6/h1-5H

InChI key

ORVMIVQULIKXCP-UHFFFAOYSA-N

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General description

Trifluoro(phenyl)silane can react with aliphatic alcohols to yield benzene and alkoxyfluoro and tetraalkoxysilanes. Hydrolytic condensation of this silane in its vapor phase results in the formation of 1,1,3,3-Tetrachloro-1,3-diphenyldisiloxane.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H312,H314

Hazard Classifications

Acute Tox. 4 Dermal - Eye Dam. 1 - Skin Corr. 1A

Supplementary Hazards

EUH014,EUH071

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

440108-100ML:4548173356877
440108-BULK:
440108-1L:4548173356884
440108-250ML:
440108-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW8884
MKCL0697
SHBF2125V
SHBF0399V
SHBD6892V

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Phenylsilane

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Journal of hazardous materials, 336, 222-231 (2017-05-12)
In this study, a novel strategy was developed to fabricate highly flame retardant polymer foam composite materials coated by synthesized silicone resin (SiR) polymer via a facile dip-coating processing. Applying the SiR polymer coating, the mechanical property and thermal stability
Syntheses and structural analyses of 1, 3-diphenyldisiloxanes as a building block of silsesquioxanes.
Bulletin of the Chemical Society of Japan, 76(10), 1983-19887 (2003)
Cleavage of the C-Si bond in Trifluoro (phenyl) silane with Aliphatic Alcohols.
Russ. J. Gen. Chem., 75(12), 1927-1929 (2005)
Phillip C Chambers et al.
Beilstein journal of nanotechnology, 9, 1211-1219 (2018-05-17)
Nanostructures of 4-(chloromethyl)phenyltrichlorosilane (CMPS) were used as a foundation to attach and grow heterostructures of porphyrins and organosilanes. A protocol was developed with particle lithography using steps of immersion in organosilane solutions to selectively passivate the surface of Si(111) with
Henry Grau et al.
Journal of colloid and interface science, 547, 145-152 (2019-04-06)
Wicking and percolation of a liquid in porous media is, among other factors, strongly affected by wettability of the pores. Nitrocellulose (NC) fibrous matrix impregnated with nitroglycerin (NG) is a main component of propellant formulations. Over time, NG, being a
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