P3011

Potassium thiocyanate

ReagentPlus^®, ≥99.0%

• Synonym(s): Potassium rhodanide
• Linear Formula: KSCN
• CAS Number: 333-20-0
• Molecular Weight: 97.18
• Beilstein: 3594799
• EC Number: 206-370-1
• MDL number: MFCD00011413
• UNSPSC Code: 12352302
• PubChem Substance ID: 329820159
• NACRES: NA.55
• Assay: ≥99.0%
• form: powder or crystals

Properties

• Quality Level: 100
• product line: ReagentPlus^®
• Assay: ≥99.0%
• form: powder or crystals
• pH: 5.3-8.7 (25 °C, 97.2 g/L)
• mp: 173 °C (lit.)
• SMILES string: [K]SC#N
• InChI: 1S/CHNS.K/c2-1-3;/h3H;/q;+1/p-1
• InChI key: ZNNZYHKDIALBAK-UHFFFAOYSA-M

Description

General description

Potassium thiocyanate (KSCN) is a potassium salt of thiocyanate anion. Its crystalline structure has been analyzed based on polarized infrared spectral data. The inhibition efficiency of KSCN dissolved in 1M HCl against the corrosion of carbon-steel has been evaluated. It facilitates the ring opening of aziridines with high regioselectivity.

Application

Potassium thiocyanate may be used in the synthesis of the following:

• α-Amino nitriles from tertiary amines.
• Polysubstituted 2-aminothiazoles from vinyl azides.
• Benzisothiazol-3(2H)-one derivatives from o-bromobenzamides.
• Diaryl thioethers from aryl halides.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H302 + H312 + H332,H318,H412
• Precautionary Statements: P273 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1
• Supplementary Hazards: EUH032
• Storage Class Code: 13 - Non Combustible Solids
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable